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Vapour pressure of pure water at 298 K ...

Vapour pressure of pure water at `298 K ` is `23.8 mm Hg`. `50g` of urea `(NH_(2)CONH_(2))` is dissolved in `850g` of water. Calculate the vapour pressure of water for this solution and its relative lowering.

Text Solution

Verified by Experts

Moles of urea `= (50)/(60) = 0.833`
Moles of water `= (850)/(18) = 47.222`
Mole fraction of urea `= (0.833)/(0.833 + 47.222) = 0.0173`
`(p_(A)^(@) - p_(A))/(p_(A)^(@)) = x_(B) = 0.0173`
`(23.8-p_(A))/(23.8) = 0.0173`
`23.8-p_(A) = 0.412`
`p_(A) = 23.39`
Relative lowering of vapour pressure = 0.0173.
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