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K(2)HgI(4) is 40% ionised in aqueous so...

`K_(2)HgI_(4)` is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is :

A

1.8

B

2.2

C

2

D

1.6

Text Solution

Verified by Experts

The correct Answer is:
A

`K_(2)[HgI_(4)] = 2K^(+) + [HgI_(4)]^(-2)`
Moles of solute left undissoicated =`1 - (40)/(100) = 0.6`
Moles of solute formed `= 0.4 xx 3 = 1.2`
Total moles of solute ` = 1.2 +0.6=1.8`
`I = (1.8)/(1) = 1.8`
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