Home
Class 12
CHEMISTRY
Calculate the degree of dissociation (al...

Calculate the degree of dissociation `(alpha)` of acetic acid if its molar conductivity `(^^_(m))` is 39.05 `S cm^(2) mol^(-1)`
Given `lamda^(@) (H^(+)) = 349.6 cm^(2) mol^(-1) and lamda^(2) (CH_(3)COO^(-)) = 40.9 S cm^(2) mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
0.1

`Lambda^(@) (CH_(3) COOH) = lambda^(@) (CH_(3) COO^(-)) + lambda^(@) (H^(+))`
`=40.9 + 349.6`
`= 390.5 S cm^(2) mol^(-1)`
`Lambda = 39.05 S cm^(2) mol^(-1)`
`alpha = (Lambda^(c))/(Lambda_(0)) = (39.05)/(390.5)`
= 0.10 or 10 %
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    MODERN PUBLICATION|Exercise CONCEPTUAL QUESTIONS|51 Videos
  • ELECTROCHEMISTRY

    MODERN PUBLICATION|Exercise NCERT FILE NCERT (IN -TEXT QUESTIONS)|15 Videos
  • ELECTROCHEMISTRY

    MODERN PUBLICATION|Exercise PROBLEMS|11 Videos
  • D AND F-BLOCK ELEMENTS

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|12 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    MODERN PUBLICATION|Exercise COMPETION FILE (Integer Type Numerical Value Type Questions)|5 Videos

Similar Questions

Explore conceptually related problems

(a) Calculate the degree of dissociation of 0.0024 M acetic acid if conductivity of this solution is 8.0 xx 10^(-5)" S "cm^(-1) . Given . lambda_(H^(+))^(@) = 349.6" S " cm^(2)" mol"^(-1), lamda_(CH_(3)COO^(-))^(@)= 40.9" S " cm^(2) " mol "^(-1) (b) Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The limiting molar conductivity of ‘B’ increases to a smaller extent while that of ‘A’ increases to a much larger extent comparatively. Which of the two is a strong electrolyte? Justify your answer.

Calculate degree of dissocation of 0.02 M acetic acid at 298K. Given that Lamda_(m) (CH_(3)COOH)= 17.37 S cm^(2) mol^(-1), lamda_(m)^(@) (H^(+)) = 345.8 S cm^(2) mol^(-1), lamda_(m)^(@) (CH_(3)COO^(-)) = 40.2S cm^(2) mol^(-1)

Calculate degree of dissociation of 0.02 M acetic acid at 298 K given that mho_(m)(CH_(3)COOH)=17.37 cm^(2) mol^(-1),lambda_(m)^(@)(H+)=345.8 S cm^(2) mol^(-1), lambda_(m)^(@)(CH_(3)COO^(-))=40.2 Scm^(2) mol^(-1)

The conductivity of 0.001 "mol" L^(-1) solution of CH_(3)COOH " is " 3.905 xx 10^(-5) "S" cm^(-1) . Calculate its molar conductivity and degree of dissociation (alpha) . "Given" lambda^(@) (H^(+)) = 349.6 "S" cm^(2) "mol"^(-1) " and " lambda^(0) (CH_(3)COO^(-)) = 40.9 "S" cm^(2) "mol"^(-1) (b) Define electrochemical cell. What happens if external potential applied becomes greater than E_(cell)^(@) of electrochemical cell?

MODERN PUBLICATION-ELECTROCHEMISTRY -PRACTICE PROBLEMS
  1. Specific conductivity of N/35 KCl at 298 K is 0.002768 ohm^(-1) cm^(-1...

    Text Solution

    |

  2. The molar conductivity of KCl solution at different concentrations at ...

    Text Solution

    |

  3. Calculate the degree of dissociation (alpha) of acetic acid if its mol...

    Text Solution

    |

  4. Calculate the molar conductivity at infinite dilution of AgCl from the...

    Text Solution

    |

  5. The Lambda^(@) values of KNO3 and LiNO3 are 145.0 and 110.1 S cm^(2) ...

    Text Solution

    |

  6. The conductivity of 0.001 mol L^(-1) solution of CH(3)COOH is 3.905xx1...

    Text Solution

    |

  7. Molar conductivities at infinite dilution (at 298 K) of NH(4)CI, NaOH ...

    Text Solution

    |

  8. Molar conductivities at infinite dilution (at 298 K) of NH(4)CI, NaOH ...

    Text Solution

    |

  9. The conductivity of 0.1 M solution of AgNO3 is 9.47 xx 10^(-3) S cm^(-...

    Text Solution

    |

  10. The molar conductivity of 0.025 mol L^(-1) methanoic acid is 46.1 S cm...

    Text Solution

    |

  11. wedge^(@).(m) for CaCl(2) and MgSO(4) from the given data. lambda(C...

    Text Solution

    |

  12. The conductivity of 0.001028 mol L ^(-1) acetic acid is 4.95 xx10^(-5)...

    Text Solution

    |

  13. At 25^(@)C, the molar conductances at infinite dilution for the strong...

    Text Solution

    |

  14. The conductivity of a saturated solution of BaSO(4) at 298 K , is foun...

    Text Solution

    |

  15. An iron wire is immersed in a solutin containg ZnSO(4) and NiSO(4). Pr...

    Text Solution

    |

  16. Can a solution of 1 M copper sulphate be stored in a vessel made of ni...

    Text Solution

    |

  17. What is the standard e.m.f of the cell containing Sn^(2+)|Sn and Br2 ...

    Text Solution

    |

  18. Calculate the standard reduction potential of Ag^(+)|Ag electrode when...

    Text Solution

    |

  19. Calculate the standard cell potential of galvanic cell in which the fo...

    Text Solution

    |

  20. Calculate the standard reduction potentials of galvanic cells in which...

    Text Solution

    |