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A copper wire is dipped in silver nitrat...

A copper wire is dipped in silver nitrate solution in beaker A and a silver wire is dipped in a solution of copper sulphate kept in a beaker B . If the standard electrode potential for
`Cu^(2+) + 2e^(-) to Cu` is +0.34 for `Ag^(+) + e^(-) to Ag` is 0.80 V
Predict in which beaker the ions present will get reduced ?

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The correct Answer is:
To solve the problem, we need to analyze the two beakers and the reactions that take place in each when the respective wires are dipped in the solutions. ### Step-by-Step Solution: 1. **Identify the Solutions and Wires:** - Beaker A contains silver nitrate (AgNO₃) solution with a copper wire. - Beaker B contains copper sulfate (CuSO₄) solution with a silver wire. 2. **Standard Electrode Potentials:** - For the reduction half-reaction of copper: \[ \text{Cu}^{2+} + 2e^- \rightarrow \text{Cu} \quad E^\circ = +0.34 \, \text{V} \] - For the reduction half-reaction of silver: \[ \text{Ag}^+ + e^- \rightarrow \text{Ag} \quad E^\circ = +0.80 \, \text{V} \] 3. **Determine the Tendency of Reduction:** - A higher standard electrode potential indicates a greater tendency for the species to be reduced. - Comparing the two potentials: - Silver (Ag) has a higher potential (+0.80 V) than copper (+0.34 V). - Therefore, Ag⁺ ions will have a stronger tendency to be reduced compared to Cu²⁺ ions. 4. **Reactions in Each Beaker:** - **In Beaker A (Cu wire in AgNO₃):** - The reaction involves the reduction of Ag⁺ ions: \[ \text{Ag}^+ + e^- \rightarrow \text{Ag} \quad (\text{Ag is reduced}) \] - Copper wire does not get oxidized because Ag⁺ has a higher tendency to be reduced. - **In Beaker B (Ag wire in CuSO₄):** - The reaction involves the oxidation of Ag: \[ \text{Ag} \rightarrow \text{Ag}^+ + e^- \quad (\text{Ag is oxidized}) \] - Cu²⁺ ions do not get reduced because Ag wire will lose electrons instead. 5. **Conclusion:** - The ions present in Beaker A (Ag⁺) will get reduced to Ag. - The ions present in Beaker B (Cu²⁺) will not be reduced; instead, Ag will be oxidized. ### Final Answer: The ions present in Beaker A will get reduced.

To solve the problem, we need to analyze the two beakers and the reactions that take place in each when the respective wires are dipped in the solutions. ### Step-by-Step Solution: 1. **Identify the Solutions and Wires:** - Beaker A contains silver nitrate (AgNO₃) solution with a copper wire. - Beaker B contains copper sulfate (CuSO₄) solution with a silver wire. ...
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