Home
Class 12
CHEMISTRY
On nuclear chlorination, C(8), H(10) (A)...

On nuclear chlorination, `C_(8), H_(10) (A)` gives a product `(B)` which may be oxidised to `C_(8) H_(5)O_(4)Cl(C). (A)` may alos be chlorinated to give `C_(8) H_(8) Cl_(2)(D), C_(8) H_(6)Cl_(4)(E)`, and `C_(8) H_(4) Cl_(6)(F). (D), (E)` and `(F)` on hydrolysis give halogen-free compounds `(G), (H)`, and `(I)`, respectively. With `CrCO_(2)Cl_(2), (A)` gives `C_(8) H_(6)O_(4)` which is identiacla with `(I)` . Identify wtih `(I)`. Identify the varioius compounds `(A)` to `(J)`.

Text Solution

Verified by Experts

`4 D.U` in `(A)` suggests benzene ring with two `(Me)` groups on `p-` psotion since one product on mono-chlorination `(OMP = 231)`
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY|Exercise Exercises Concept Application Type|2 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY|Exercise Exercises Concept Application|4 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY|Exercise Exercises Subjective Type|4 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos
CENGAGE CHEMISTRY-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Subjective
  1. Give the chemical test to distinguish between (a) Hexane (I), MeCH=C...

    Text Solution

    |

  2. Give the product of E2 reaction of the following compounds with atc. K...

    Text Solution

    |

  3. Draw the diastermers of 2- chloro -1,3- dimethyl cyclohexane and indi...

    Text Solution

    |

  4. Draw the diastermers of 2- chloro -1,3- dimethyl cyclohexane and indi...

    Text Solution

    |

  5. (W) and (X) are optically active isomers of C(5) H(9) Cl (W) on treatm...

    Text Solution

    |

  6. An organic compound (A), C(8)H(4) O(3) in dry benzene in the presene ...

    Text Solution

    |

  7. Three isomeric hydrocations C(9) H(12) [(A),(B),(C)] oxide to C(9) H(...

    Text Solution

    |

  8. An organtiic compound (A) contains C = 92.3% and H = 7.7% Its vapour d...

    Text Solution

    |

  9. An aromatic hydrocarbobn (A) containing C = 91.3% and H = 8.7% on tre...

    Text Solution

    |

  10. Compound C(8)H(9)Cl (A) on treatment with KICN followedd by hydrolysi...

    Text Solution

    |

  11. ON disuphonatioon followed by fusion with NaOH an dacidificant, an aro...

    Text Solution

    |

  12. The compoiund (A0 is xylene. On sulphonation, it gives only one produ...

    Text Solution

    |

  13. An organci compound C(6) H(4) O(2) NCl (A) reacts with a,la,oo tp gove...

    Text Solution

    |

  14. A hydrocarbon C(9) H(10) (A) rapidly decolourises cold aquous permanga...

    Text Solution

    |

  15. On nuclear chlorination, C(8), H(10) (A) gives a product (B) which may...

    Text Solution

    |

  16. When boromobenze is monochlorinated. Two ismoeic compounds (A) and (B)...

    Text Solution

    |

  17. 0.450 gm of an aromatic organic compound (A) on ignitin gives 0.905 g...

    Text Solution

    |