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Molecules of ethanoic acid in water dime...

Molecules of ethanoic acid in water dimerise when dissolved in :

A

water

B

benzene

C

glycerine

D

ethyl alcohol

Text Solution

Verified by Experts

The correct Answer is:
B

benzene
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Read the given passage and answer the questions : Molecules of ethanoic acid dimerise in benzene due to hydrogen bonding. This normally happens in solvents of low dielectric constant. In this case, the number of particles is reduced due to dimerisation. The molar mass calculated on the basis of this Delta T_b or Delta T_f will, therefore, be twice the expected value. Such a molar mass that is either lower or higher than the expected or normal value is called as abnormal molar mass. Why does ethanoic acid dimerise in benzene solution ?

Read the given passage and answer the questions : Molecules of ethanoic acid dimerise in benzene due to hydrogen bonding. This normally happens in solvents of low dielectric constant. In this case, the number of particles is reduced due to dimerisation. The molar mass calculated on the basis of this Delta T_b or Delta T_f will, therefore, be twice the expected value. Such a molar mass that is either lower or higher than the expected or normal value is called as abnormal molar mass. Write the structure of dimerised ethanoic acid.

Knowledge Check

  • Solute when dissolved in water:

    A
    increases the vapour pressure of water
    B
    decreases the boiling point of water
    C
    decreases the freezing point of water
    D
    all of the above
  • Solute when dissolve in water

    A
    increases the vapour pressure of water
    B
    decreases the boiling point of water
    C
    decrease the freezing point of water
    D
    All of the above
  • The molecular mass of acetic acid dissolved in water is 60 and when dissolved in benzene it is 120. This difference in behaviour of CH_(3)COOH is because

    A
    Water prevents association of acetic acid
    B
    Acetic acid does not fully dissolve in water
    C
    Acetic acid fully dissolves in benzene
    D
    Acetic acid does not ionize in benzene
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    The molecular mass of acetic acid dissolved in water is less than 60, and when dissolved in benezene it is 120 . This difference in behaviour of CH_(3)COOH is because _______.