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Calculate the standard enthalpy of formation of `CH_(3)OH(l)` from the following data:
`CH_(3)OH(l)+3/2O_(2)(g) rarr CO_(2)(g)+2H_(2)O(l), …(i), Delta_(r)H_(1)^(Θ)=-726 kJ mol^(-1)`
`C(g)+O_(2)(g) rarr CO_(2)(g), …(ii), Delta_(c )H_(2)^(Θ)=-393 kJ mol^(-1)`
`H_(2)(g)+1/2O_(2)(g) rarr H_(2)O(l), ...(iii), Delta_(f)H_(3)^(Θ)=-286 kJ mol^(-1)`

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To calculate the standard enthalpy of formation of \( CH_3OH(l) \), we will use Hess's law, which states that the total enthalpy change for a reaction is the sum of the enthalpy changes for the individual steps of the reaction. ### Given Data: 1. Reaction (i): \[ CH_3OH(l) + \frac{3}{2} O_2(g) \rightarrow CO_2(g) + 2 H_2O(l), \quad \Delta_r H_1^\Theta = -726 \, \text{kJ/mol} \] 2. Reaction (ii): \[ C(g) + O_2(g) \rightarrow CO_2(g), \quad \Delta_c H_2^\Theta = -393 \, \text{kJ/mol} \] 3. Reaction (iii): \[ H_2(g) + \frac{1}{2} O_2(g) \rightarrow H_2O(l), \quad \Delta_f H_3^\Theta = -286 \, \text{kJ/mol} \] ### Steps to Calculate the Standard Enthalpy of Formation of \( CH_3OH(l) \): 1. **Write the formation reaction for \( CH_3OH(l) \)**: The standard enthalpy of formation is defined for the formation of one mole of a compound from its elements in their standard states. The reaction can be written as: \[ C(s) + 2 H_2(g) + \frac{1}{2} O_2(g) \rightarrow CH_3OH(l) \] 2. **Reverse Reaction (i)**: To find the enthalpy of formation, we need to reverse Reaction (i): \[ CO_2(g) + 2 H_2O(l) \rightarrow CH_3OH(l) + \frac{3}{2} O_2(g) \] The enthalpy change for this reversed reaction will be: \[ \Delta_r H = +726 \, \text{kJ/mol} \] 3. **Use Reaction (ii)**: The enthalpy change for Reaction (ii) is already given as: \[ C(g) + O_2(g) \rightarrow CO_2(g), \quad \Delta_c H = -393 \, \text{kJ/mol} \] 4. **Use Reaction (iii)**: Since we need 2 moles of \( H_2O(l) \), we will multiply Reaction (iii) by 2: \[ 2 H_2(g) + O_2(g) \rightarrow 2 H_2O(l), \quad \Delta_f H = 2 \times (-286) = -572 \, \text{kJ/mol} \] 5. **Combine the Reactions**: Now we can combine the enthalpy changes: \[ \Delta H_f^\Theta (CH_3OH) = \Delta H_1 + \Delta H_2 + \Delta H_3 \] Substituting the values: \[ \Delta H_f^\Theta (CH_3OH) = (+726) + (-393) + (-572) \] \[ \Delta H_f^\Theta (CH_3OH) = 726 - 393 - 572 \] \[ \Delta H_f^\Theta (CH_3OH) = -239 \, \text{kJ/mol} \] ### Final Answer: The standard enthalpy of formation of \( CH_3OH(l) \) is \( -239 \, \text{kJ/mol} \).

To calculate the standard enthalpy of formation of \( CH_3OH(l) \), we will use Hess's law, which states that the total enthalpy change for a reaction is the sum of the enthalpy changes for the individual steps of the reaction. ### Given Data: 1. Reaction (i): \[ CH_3OH(l) + \frac{3}{2} O_2(g) \rightarrow CO_2(g) + 2 H_2O(l), \quad \Delta_r H_1^\Theta = -726 \, \text{kJ/mol} \] ...
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Compounds with carbon-carbon double bond, such as ethylene, C_(2)H_(4) , add hydrogen in a reaction called hydrogenation. C_(2)H_(4)(g)+H_(2)(g) rarr C_(2)H_(6)(g) Calculate enthalpy change for the reaction, using the following combustion data C_(2)H_(4)(g) + 3O_(2)(g) rarr 2CO_(2)(g) + 2H_(2)O(g) , Delta_("comb")H^(Θ) = -1401 kJ mol^(-1) C_(2)H_(6)(g) + 7//2O_(2)(g)rarr 2CO_(2) (g) + 3H_(2)O(l) , Delta_("comb")H^(Θ) = -1550kJ H_(2)(g) + 1//2O_(2)(g) rarr H_(2)O(l) , Delta_("comb")H^(Θ) = -286.0 kJ mol^(-1)

Methanol can be prepared synthetically by heating carbon monoxide and hydrogen gases under pressure in the presence of a catalyst. The reaction is CO(g) +2H_(2)(g) rarr CH_(3)OH(l) Determine the enthalpy of this reaction by an appropriate combinantion of the following data: a. C_(("graphite")) +(1)/(2)O_(2)(g) rarr CO(g), DeltaH^(Theta)=- 110.5kJ mol^(-1) b. C_(("graphite")) +O_(2)(g) rarr CO_(2)(g), DeltaH^(Theta) =- 393.5 kJ mol^(-1) c. H_(2)(g) +(1)/(2)O_(2)(g) rarr H_(2)O(l), DeltaH^(Theta) =- 285.9kJ mol^(-1) d. CH_(3)OH(l) +(3)/(2)O_(2)(g)rarr CO_(2)(g) +2H_(2)O(l),DeltaH^(Theta) =- 726.6 kJ mol^(-1)

Calculate the heat of formation of methanol (CH_3OH) from thhe following data: CH_3OH(l) + 3/2O_2(g) to CO_2(g) + 2H_2O (l),Delta =-726 kJ C(s) + O_2(g) to CO_2(g) , DeltaH = -394 kJ H_2(g) + 1/2 O_2(g) to H_2O(l) , Delta H = -286 kJ

Calculate enthalpy of formation of methane (CH_4) from the following data : (i) C(s) + O_(2)(g) to CO_(2) (g) , Delta_rH^(@) = -393.5 KJ mol^(-1) (ii) H_2(g) + 1/2 O_(2)(g) to H_(2)O(l) , Deta_r H^(@) = -285.5 kJ mol^(-1) (iii) CH_(4)(g) + 2O_(2)(g) to CO_(2)(g) + 2H_(2)O(l), Delta_(r)H^(@) = -890.3 kJ mol^(-1) .

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Calculate the enthalpy of formation of Delta_(f)H for C_(2)H_(5)OH from tabulated data and its heat of combustion as represented by the following equaitons: i. H_(2)(g) +(1)/(2)O_(2)(g) rarr H_(2)O(g), DeltaH^(Theta) =- 241.8 kJ mol^(-1) ii. C(s) +O_(2)(g) rarr CO_(2)(g),DeltaH^(Theta) =- 393.5kJ mol^(-1) iii. C_(2)H_(5)OH (l) +3O_(2)(g) rarr 3H_(2)O(g) + 2CO_(2)(g), DeltaH^(Theta) =- 1234.7kJ mol^(-1)

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