Home
Class 11
CHEMISTRY
For an isolated system, DeltaU=0, what w...

For an isolated system, `DeltaU=0`, what will be `Delta S`?

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question "For an isolated system, if ΔU = 0, what will be ΔS?", we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Concept of an Isolated System**: An isolated system is one that does not exchange energy or matter with its surroundings. Therefore, any changes occurring within the system must conserve energy. 2. **Identify the Given Information**: We are given that for the isolated system, the change in internal energy (ΔU) is equal to 0. 3. **Apply the First Law of Thermodynamics**: The First Law of Thermodynamics states that the change in internal energy (ΔU) of a system is equal to the heat added to the system (Q) minus the work done by the system (W): \[ \Delta U = Q - W \] Since ΔU = 0, we have: \[ Q = W \] This means that any heat added to the system is exactly balanced by the work done by the system. 4. **Consider the Entropy Change (ΔS)**: For spontaneous processes, the total entropy of an isolated system must increase. The second law of thermodynamics states that the entropy of an isolated system will either increase or remain constant; it cannot decrease. 5. **Conclusion**: Since ΔU = 0 for the isolated system and considering spontaneous processes, we conclude that: \[ \Delta S > 0 \] Therefore, the change in entropy (ΔS) must be greater than zero. ### Final Answer: For an isolated system where ΔU = 0, ΔS must be greater than 0 (ΔS > 0). ---

To solve the question "For an isolated system, if ΔU = 0, what will be ΔS?", we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Concept of an Isolated System**: An isolated system is one that does not exchange energy or matter with its surroundings. Therefore, any changes occurring within the system must conserve energy. 2. **Identify the Given Information**: ...
Promotional Banner

Topper's Solved these Questions

  • THE S-BLOCK ELEMENTS

    NCERT ENGLISH|Exercise EXERCISE|32 Videos

Similar Questions

Explore conceptually related problems

Define isolated system.

For an isolated system, the entropy :

What is an isolated system ?

A : For an isolated system Delta G = - TDeltaS_("total") R: For an isolated system q = 0.

An isolated system is that system in which

An isolated system is that system in which

An isolated system is that system in which

Assertion:- If at t=0, centre of mass of an isolated system is at (0,1,2) than at t=2h,25 min, its centre of mass may be (0,1,2). Reason:- For a isolated system, velocity of the centre of mass is constant.

The gravitational potential energy of an isolated system of three particles, each of mass m , at the three corners of an equilateral triangle of side l is

Assertion : In an isolated system the entropy increases. Reason : The processes in an isolated system are adiabatic.

NCERT ENGLISH-THERMODYNAMICS-All Questions
  1. one mole an ideal gas having volume 2 litre and at a pressure of 10...

    Text Solution

    |

  2. If water vapour is assumed to be a perfect gas, molar enthalpy change ...

    Text Solution

    |

  3. Calculate DeltaG^(Theta) for the conversion of oxygen to ozone, ((3)/(...

    Text Solution

    |

  4. Find out the value of equilibrium constant for the following reaction ...

    Text Solution

    |

  5. Choose the correct answer. A thermodynamic state function is a quanti...

    Text Solution

    |

  6. The enthalpy of combustion of methane, graphite and dihydrogen at 298 ...

    Text Solution

    |

  7. In a process, 701 J of heat is absorbed by a system and 394 J of work ...

    Text Solution

    |

  8. The reaction of cyanamide, NH(2)CN(s), with dioxygen was carried out i...

    Text Solution

    |

  9. Calculate the number of kJ of heat necessary to raise the temperature ...

    Text Solution

    |

  10. Find the value of Delta(f) H^(@) for the reaction N(2) O(4) (g) + 3 ...

    Text Solution

    |

  11. Given N(2)(g)+3H(2)(g)rarr2NH(3)(g),Delta(r)H^(Ө)= -92.4 kJ mol^(-1...

    Text Solution

    |

  12. Calculate the standard enthalpy of formation of CH(3)OH(l) from the fo...

    Text Solution

    |

  13. Calculate the enthalpy change for the process C Cl(4)(g) rarr C(g)+4...

    Text Solution

    |

  14. For an isolated system, DeltaU=0, what will be Delta S?

    Text Solution

    |

  15. For the reaction at 298 K 2A+B rarr C DeltaH=400 kJ mol^(-1) and D...

    Text Solution

    |

  16. For the reaction 2Cl(g) rarr Cl(2)(g), what are the signs of DeltaH ...

    Text Solution

    |

  17. For the reaction, 2A(g)+B(g) rarr 2D(g) DeltaU^(Θ)=-10.5 kJ and De...

    Text Solution

    |

  18. The equilibrium constant for a reaction is 10. What will be the value ...

    Text Solution

    |

  19. Comment on the thermodynamic stability of NO(g), given 1/2N(2)(g)+1/...

    Text Solution

    |

  20. Calculate the entropy change in surroundings when 1.00 mol of H(2)O(l)...

    Text Solution

    |