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Suggest reasons why the B–F bond lengths...

Suggest reasons why the B–F bond lengths in `BF_(3)` (130 pm) and `BF_(4 )^(– )`(143 pm) differ.

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To understand why the B–F bond lengths in BF₃ (130 pm) and BF₄⁻ (143 pm) differ, we can analyze the bonding characteristics and electronic structure of both molecules. Here’s a step-by-step breakdown of the reasoning: ### Step 1: Analyze the Electronic Configuration of Boron - Boron (B) has an atomic number of 5, with an electronic configuration of 1s² 2s² 2p¹. This means it has three valence electrons available for bonding. **Hint:** Consider how the valence electrons of boron participate in bond formation with fluorine. ### Step 2: Bond Formation in BF₃ ...
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NCERT ENGLISH-THE P-BLOCK ELEMENTS -EXERCISE
  1. Explain the difference in properties of diamond and graphite on the ba...

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  2. Rationalise the given statements and give chemical reactions. a. Lea...

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  3. Suggest reasons why the B–F bond lengths in BF(3) (130 pm) and BF(4 )^...

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  4. If B-Cl bond has a dipole moment, explain why BCl(3) molecule has zero...

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  5. AlF(3) is insoluble in anhydrous HF but dissolves on addition of NaF. ...

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  6. Suggest a reason as to why CO is poisonous.

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  7. How is excessive content of CO(2) responsible for global warming?

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  8. Explain structures of diborane and boric acid.

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  9. What happens when (a) Borax is heated strongly, (b) Boric acid is ...

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  10. Explain the following reactions (a) Silicon is heated with methyl ch...

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  11. Give reasons : (i) Conc. HNO(3) can be transported in aluminium con...

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  12. Explain why is there a phenomenal decrease in ionisation enthalpy from...

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  13. How would you explain the lower atomic radii of Ga as compared to Al?

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  14. What are allotropes? Sketch the structure of two allotropes of carbon ...

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  15. a. Classify following oxides as neutral, acidic, basic or amphoteric: ...

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  16. In some of the reactions, thallium resembles aluminium whereas in othe...

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  17. When metal X is treated with sodium hydroxide, a white precipitate (A)...

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  18. What do you understand by (a) inert pair effect (b) allotropy and (c...

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  19. A certain salt (X) gives the following tests : (a) Its aqueous solut...

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  20. Write balanced equations for: a.BF(3)+LiHto b.B(2)H(6)+H(2)Oto c...

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