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Why is Cr^(2+) reducing and Mn^(3+) oxid...

Why is `Cr^(2+)` reducing and `Mn^(3+)` oxidising when both have `d^4` configuration?

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To understand why \( \text{Cr}^{2+} \) is a reducing agent and \( \text{Mn}^{3+} \) is an oxidizing agent despite both having a \( d^4 \) configuration, we can break down the explanation into clear steps: ### Step 1: Determine the electronic configurations 1. **Chromium (Cr)**: - Atomic number: 24 - Electronic configuration: \( [\text{Ar}] 3d^5 4s^1 \) - For \( \text{Cr}^{2+} \), it loses two electrons (one from \( 4s \) and one from \( 3d \)): ...
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(a) What happens when (i) Manganate ions (MnO_(4)^(2-)) undergoes disproportionation reaction in acidic medium ? (ii) Lanthanum is heated with Sulphur? (b) Explain the following trends in the properties of the members of the First series of transition elements: (i) E^(@) (M^(2+)//M) value for copper is positive (+ 0.34 V) in contrast to the other members of the series. (ii) Cr^(2+) is reducing while Mn^(3+) is oxidising, though both have d^(4) configuration. (iii) The oxidising power in the series increases in the order VO_(2)^(+) lt Cr_(2)O_(7)^(2-) lt MnO_94)^(-) .

Assertion : Cr^(2+) is reducing and Mn^(3+) is oxidising. Reason : Cr^(2+) and Mn^(3+) have d^4 configuration.

Assertion :- Cr^(+2) is a reducing agent and Mn^(+3) is oxidising agent. Reason :- Mn^(+3) has d^(5) configuration.

How would you account for the following : (i) Cr^(2+) is reducing in nature while with the same d-orbital configuration (d^(4)),Mn^(2+) is oxidising in nature. (ii) In the transition series of metals, the metal which exhibits the greatest number of oxidation states occurs in the middle of the series.

Explain the following observations: (i) Transition elements are known to form many interstitial compounds.. (ii) With the same d^4 configuration Cr^(2+) ion is reducing while Mn^(3+) ion is oxidising. (iii) The enthalpies of atomization of the transition elements are quite high.

Four statements for Cr and Mn are given below: (i) Cr^(2+) and Mn^(3+) have the same electronic configuration. (ii) Cr^(2+) is a reducing agent while Mn^(3+) is an oxidising agent. (iii) Cr^(3+) is an oxidizing agent while Mn^(3+) is a reducing agent. (iv). both Cr and Mn are oxidizing agents. The correct statemetns are

Which of the following statement are correct about Cr^(2+) (Z = 24) and Mn^(3+) (Z = 25) ? (i) Cr^(2+) is a reducing agent (ii) Mn^(3+) is an oxidizing agent (iii) Both Cr^(2+) and Mn^(3+) exhibit d^(4) configuration (iv) When Cr^(2+) is used as a reducing agent, the chromium ion attains d^(5) electronic configuration

H_(2)S acts only as reducing agent while SO_(2) can act both as a reducing agent and as an oxidising agent. How will you account for it ?

Give reasons for the following: (1) HNO_3 acts only as an oxidising agent while HNO_2 can act both as a reducing agent and an oxidising agent (2) Chlorine liberates iodine from Kl solution.

Which of the following is true for the speical having 3d^(4) configuration ?

NCERT ENGLISH-THE D AND F BLOCK ELEMENTS-Exercise
  1. Why is Cr^(2+) reducing and Mn^(3+) oxidising when both have d^4 confi...

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  2. Write down the electronic configuration of: (i). Cr^(3+) (ii). Prn...

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  3. Why are Mn^(2+) compounds more stable than Fe^(2+) toward oxidation to...

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  4. Explain briefly how +2 state become more and stable in the first half ...

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  5. To what extent do the electronic configurations, decide the stability ...

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  6. What may be the stable oxidation state of the transition element with ...

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  7. Name the oxometal anions of the first series of the transition metals ...

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  8. What is lanthanoid contraction? What are the consequences of lanthanol...

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  9. What are the characteristics of th transition elements and why are the...

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  10. In What way is the electronic configuration of the transition elements...

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  11. What are the different oxidation states exhibited by the lanthanoids?

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  12. Explain gives reason. (a) Transition metal and many of their compoun...

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  13. What are interstitial compounds? Why are such compounds well known for...

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  14. How is the variability in oxidation states of transition metals differ...

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  15. Describe the preparation of potassium dichromate from iron chromite or...

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  16. Describe the oxidising action of potassium dichromate and write the io...

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  17. Describe the preparation of potassium permanganate. How does the acidi...

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  18. For (M^(2+))/(M) and (M^(3+))/(M^(2+)) systems the E^(ɵ) values for so...

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  19. Predict which of the followingwill be coloured in aqueous solution? T...

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  20. Compare the stability of +2 oxidation state for the elements of the fi...

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  21. Compare the chemistry of actinoids with that of the lanthanoids with s...

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