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Derive an intergrated rate for the first...

Derive an intergrated rate for the first order reaction.

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The rate of the reaction is directly proportional to the `1^(@)` power of the concentration of reactant R.
`R rarr P`
rate `= (-d[R])/(dt) = k[R]`
`(d[R])/(dt) = -K[R]` or `(d[R])/([R]) = -K dt`
Integration both sides
`int. (d[R])/([R]) = -intK dt`
`log = R = -Kt + I` ....(1)
Where I is integration constant.
To find I when `t = 0, [R] = [R_(0)]`
`log[R_(0)] - K xx 0 + I`
`I = log[R_(0)]`
Substituting in (1) we get
`log R_(0) = log R = Kt`
`ln.([R_(0)])/([R]) = Kt`
or `K = (1)/(t)ln.([R_(0)])/([R])`
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OSWAAL PUBLICATION-CHEMICAL KINETICS-Topic - 2 (ORDER OF A REACTION , INTEGRATED RATE EQUATIONS AND HALF LIFE OF A REACTION ) ( Long Answer Type Questions - I)
  1. Derive the integrated rate equation for rate constant of Zero order re...

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  2. Derive an intergrated rate for the first order reaction.

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  3. Thermal decomposition of a compound is of first order. If 50% of the c...

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  4. Rate constant of a first order reaction A products is 0.016 min^(-1). ...

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  5. The following data were obtained during the first order thermal decomp...

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  6. Rate constant k for a first order reactions has been found to be 2.54 ...

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  7. With the help of a diagram, explain the physical significance of energ...

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  8. The rate of a reaction becomes four times when the temperature changes...

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  9. The rate of most reactions becomes double when their temperature is ra...

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  10. Rate constant of reaction at 300 K and 400 K are 0.0345 S^(-1) and 0.1...

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  11. The rate constant of a first order reaction at 300 K and 310 K are res...

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  12. Define energy of activation. Draw a diagram of energy profile to show ...

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  13. Half life of a first order reaction completes in 5 minutes. What perse...

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  14. With graphical representation explain the effect of temperature on the...

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  15. What will be the effect of temperature on rate constant ?

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  16. The decomposition of A into products has a value of k as 4.5 xx 10^(3)...

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  17. In general it is observed that the rate of a chemical reaction doubles...

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