Home
Class 12
CHEMISTRY
In general it is observed that the rate ...

In general it is observed that the rate of a chemical reaction doubles with every 10 degree rise in temperature. If the generalization holds good for the reaction in the temperature range 295 K to 305 K, what would be the value of activation energy for this reaction ? `[R = 8.314 mol^(-1)JK^(-1)]`

Text Solution

Verified by Experts

`log.(K_(1))/(K_(2)) = (E)/(2.303 R)[(T_(2)-T_(1))/(T_(1) xx T_(2))]`
`log.(2)/(1) = (E_(a))/(2.303 xx 8.314)[(305-295)/(295 xx 305)]`
`0.3010 = (E_(a))/(19.14714)[(10)/(89975)]`
`E_(a) = (0.3010 xx 19.147 xx 89975)/(10)`
`E_(a) = 51906 J mol^(-1)`
`= 51.906 KJ//mol`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    OSWAAL PUBLICATION|Exercise Topic - 2 (ORDER OF A REACTION , INTEGRATED RATE EQUATIONS AND HALF LIFE OF A REACTION )Long Answer Type Questions - II)|4 Videos
  • CHEMICAL KINETICS

    OSWAAL PUBLICATION|Exercise Topic - 2 (ORDER OF A REACTION , INTEGRATED RATE EQUATIONS AND HALF LIFE OF A REACTION ) (Short Answer Type Questions)|8 Videos
  • BIOMOLECULES

    OSWAAL PUBLICATION|Exercise TOPIC -II (LONG ANSWER TYPE QUESTIONS)|2 Videos
  • CHEMISTY IN EVERYDAY LIFE

    OSWAAL PUBLICATION|Exercise LONG ANSWER TYPE QUESTIONS-I|1 Videos

Similar Questions

Explore conceptually related problems

The rate of a chemical reaction doubles for every 10^(@) C rise of temperature . If the temperature is raised by 50^(@) C the rate of the reaction increases by about :

a) The rate of a particular reaction doubles when the temperature changes from 300 K to 310 K. Calculate the energy of activation of the reaction. [Given : R="8.314 JK"^(-1)" mol"^(-1) ].

The rate of most reactions becomes double when their temperature is raised from 298 K to 308 K. Calculate their activation energy.

The rate of a chemical reaction doubles for an increase of 10K in absolute temperature from 298K. Calculate E_(a) .

OSWAAL PUBLICATION-CHEMICAL KINETICS-Topic - 2 (ORDER OF A REACTION , INTEGRATED RATE EQUATIONS AND HALF LIFE OF A REACTION ) ( Long Answer Type Questions - I)
  1. Derive the integrated rate equation for rate constant of Zero order re...

    Text Solution

    |

  2. Derive an intergrated rate for the first order reaction.

    Text Solution

    |

  3. Thermal decomposition of a compound is of first order. If 50% of the c...

    Text Solution

    |

  4. Rate constant of a first order reaction A products is 0.016 min^(-1). ...

    Text Solution

    |

  5. The following data were obtained during the first order thermal decomp...

    Text Solution

    |

  6. Rate constant k for a first order reactions has been found to be 2.54 ...

    Text Solution

    |

  7. With the help of a diagram, explain the physical significance of energ...

    Text Solution

    |

  8. The rate of a reaction becomes four times when the temperature changes...

    Text Solution

    |

  9. The rate of most reactions becomes double when their temperature is ra...

    Text Solution

    |

  10. Rate constant of reaction at 300 K and 400 K are 0.0345 S^(-1) and 0.1...

    Text Solution

    |

  11. The rate constant of a first order reaction at 300 K and 310 K are res...

    Text Solution

    |

  12. Define energy of activation. Draw a diagram of energy profile to show ...

    Text Solution

    |

  13. Half life of a first order reaction completes in 5 minutes. What perse...

    Text Solution

    |

  14. With graphical representation explain the effect of temperature on the...

    Text Solution

    |

  15. What will be the effect of temperature on rate constant ?

    Text Solution

    |

  16. The decomposition of A into products has a value of k as 4.5 xx 10^(3)...

    Text Solution

    |

  17. In general it is observed that the rate of a chemical reaction doubles...

    Text Solution

    |