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With an example explain the following: ...

With an example explain the following:
(i) Clemmensen's reduction
(ii) Kolbe's reaction.

Text Solution

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(i) When a ketone is treated with Zn-Hg/conc. HCl a hydrocarbon is obtained.
Any example with equation.
OR
When acetone/acetophenone is treated with zinc amalgam and concentrated HCl, Propane/ethyl benzene is obtained.
`CH_(3)COOCH_(3)+4[H]underset("Conc."HCl)overset(Zn-Hg)(to)CH_(3)-CH_(2)-CH_(3)+H_(2)O`
`C_(6)H_(5)COCH_(3)+4[H]underset("Conc."HCl)overset(Zn-Hg)(to)C_(6)H_(5)-CH_(2)-CH_(3)+H_(2)O`
(ii) Dry sodium phenate is heated with carbon dioxide at `140^(@)C` under 4-7 atm pressure
The product obtained an acidification gives salicylic acid.
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