Home
Class 12
CHEMISTRY
Write the mechanism of acid catalysed de...

Write the mechanism of acid catalysed dehydration of ethanol to ethene.

Text Solution

Verified by Experts

(a) When sodium phenate is heated with carbon dioxide at 413 K under 6-7 atm pressure followed by acidification with HCl, salicylic acid is formed.

(b) Step 1 : Formation of protonated alcohol :

Step 2 : Formation of carbocation :
`H-underset(H)underset(|)overset(H)overset(|)(C )-underset(H)underset(|)overset(H)overset(|)(C)-underset(ddot)overset(H)overset(|)(o^(o+))-H overset("Slow")( Step 3: Elimination of proton:
Promotional Banner

Topper's Solved these Questions

  • II PUC MARCH - 2017

    OSWAAL PUBLICATION|Exercise PART - C|8 Videos
  • II PUC APRIL - 2016

    OSWAAL PUBLICATION|Exercise PART - D|27 Videos
  • II PUC MARCH - 2018

    OSWAAL PUBLICATION|Exercise PART - D|11 Videos

Similar Questions

Explore conceptually related problems

Write the mechanism of aicd catalysed dehydration of ethanol to ethane.

(a) Explain the mechanism of acid catalysed dehydration of ethanol to ethene. (b) How do you prepare methoxy ethane. by Williamoson's ether synthesis?

(a) Explain the mechanism of acid catalysed dehydration of ethanol to (b) Write general equation for preparation of ether by Williamsonsynthesis. (c) Among alcohols and phenols which one is more acidic?

Dehydration of ethanol yields

Explain the mechanism of acid catalysed hydration of an alkene to from corresponding alcohol.

Explain the mechanism of dehydration of ethanol to ethene.