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Answer any FOUR of the following questio...

Answer any FOUR of the following questions.
b. (i) Name the main product when aniline is heated with alcoholic KOH and chloroform.
(ii) Give the IUPAC name of `(CH_3)_2 N- C_2 H_5`

Text Solution

Verified by Experts

(a) `CH_3NH_2` is more basic
`-CH_3` gp is an electron releasing group, it exerts +I effect and increases electron density on N-atom and electrons are localized on N-atom.
(b) (i) Phenyl isocyanide (Phenyl Carbylamine)
(ii) N,N-dimethylethanamine
(c ) `CH_3NH_2 + 2NaBr + Na_2CO_3 + 2H_2O or CH_3NH_2`
Detailed Answer:
(b)
(c) `CH_3CONH_2 + Br_2+ 4NaOH to CH_3NH_2 + 2NaBr + Na_2CO_3 + 2H_2O`
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