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The stable bivalency of Pb and trivalenc...

The stable bivalency of Pb and trivalency of Bi is

A

Due to d contraction in Pb and Bi

B

Due to relativistic contraction of the 6s orbitals of Pb and Bi, leading to inert pair effect

C

Due to screening effect

D

Due to attainment of noble configuration

Text Solution

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The correct Answer is:
B

In the last element of the group, after the removal of electrons from p-orbitals, the remaining `ns^(2)` electrons behave like stable noble gas and do not take part in compound formation. This reluctance of the s- electron pair to take part in chemical combination is called inert pair effect. Thus, for the elements at the bottom of a group, lower oxidation state is more stable.
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ERRORLESS -CLASSIFICATION OF ELEMENTS AND PERIODIC PROPERTIES -Ordinary Thinking Objective Questions Valency and oxidation state
  1. Which of the following electronic configuration in the outermost shell...

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  2. Which of the following elements show maximum valency ?

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  3. Fluorine is the best oxidising agent because it has

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  4. Which of the following element is found in its native state:-

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  5. The basis of keeping the elements in the group of periodic table is

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  6. Beryllium and aluminimum exhibit many properties which are similar . B...

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  7. The most stable oxidation state of thallium is +1

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  8. An element X which occurs in the second short period has an outer elec...

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  9. Which of these is the weakest base?

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  10. Fluorine, chlroine, bromine and iodine are placed in the same group (1...

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  11. the pentavalence in phosphorus is more stable as compared to that of n...

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  12. In the periodic table, the basic character of oxides

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  13. The stable bivalency of Pb and trivalency of Bi is

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  14. Which will show maximum non-metallic character

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  15. All element in 3rd period have

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  16. 3 and 6 electronic are present in the outermost orbit A and B respecti...

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  17. Elements A and B with their respective electronic configurations 3d^(...

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  18. Which of the following group of elements eliminates electron easily

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  19. An ion has 18 electrons in the outermost shell it is

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  20. Assertion : Dinegative anion of oxygen (O^(2-)) is quite common but di...

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