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Assertion : Dinegative anion of oxygen (...

Assertion : Dinegative anion of oxygen `(O^(2-))` is quite common but dinegative anion of sulphur `(S^(2-))` is less common.
Reason : Covalency of oxygen is two.

A

If both assertion and reason are true and the reason is the correct explanation of the assertion

B

If both assertion and reason are true but reason is not a correct explanation of the assertion

C

If assertion is true but reason is false

D

If the assertion and reason both are false

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The correct Answer is:
To analyze the assertion and reason provided in the question, we will break down the statements step by step. ### Step 1: Understanding the Assertion The assertion states that the dinegative anion of oxygen (O²⁻) is quite common, while the dinegative anion of sulfur (S²⁻) is less common. - **Oxygen (O)** can readily gain two electrons to form O²⁻ due to its high electronegativity and small atomic size, which allows it to stabilize the negative charge effectively. - **Sulfur (S)**, on the other hand, while it can also gain two electrons to form S²⁻, is less likely to do so because it is larger and has a lower electronegativity compared to oxygen. As a result, sulfur tends to form compounds in which it has a positive oxidation state or a lower negative oxidation state (like -2 in H₂S). ### Step 2: Understanding the Reason The reason given is that the covalency of oxygen is two. - Covalency refers to the number of bonds an atom can form. Oxygen typically forms two covalent bonds (for example, in water, H₂O). - However, the reason provided does not directly explain why the dinegative anion of sulfur is less common compared to that of oxygen. While it is true that oxygen has a covalency of two, sulfur can also exhibit a covalency of two in some compounds. ### Step 3: Evaluating the Truth of Each Statement - **Assertion**: True. The dinegative anion of oxygen (O²⁻) is common, while that of sulfur (S²⁻) is less common. - **Reason**: True, but it does not adequately explain the assertion. The covalency of oxygen being two is correct, but it does not clarify why sulfur's dinegative state is less common. ### Conclusion Based on the analysis: - The assertion is true. - The reason is true but does not provide a correct explanation for the assertion. ### Final Answer Both the assertion and reason are true, but the reason is not a correct explanation of the assertion. Therefore, the correct option is that both statements are true, but the reason is not a correct explanation of the assertion. ---
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