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Write a balanced equation for the hydrol...

Write a balanced equation for the hydrolytic reaction of `PCl_(5)` with heavy water.

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It reacts with heavy water to form phosphorus oxychloride `(POCl_(3))` and deuterium chloride (DCl)
`{:(" "PCl_(5)+D_(2)rarrPOCl_(3)+2DCl),(" "POCl_(3)+3D_(2)OrarrD_(3)PO_(4)+3DCl),(bar(" "PCl_(5)+4D_(2)OrarrD_(3)PO_(4)+5DCl" ")),(" Deuterium chloride"):}`
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OSWAAL PUBLICATION-P - BLOCK ELEMENTS-TOPIC - 1 (GROUP - 15 ELEMENTS, THEIR PROPERTIES AND SOME IMPORTANT COMPOUNDS)(SHORT ANSWER TYPE QUESTIONS)
  1. The HNH angle value is higher than HPH, HASH and HSbH angles. Why ?

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  2. Why does R(3)P = O exist but R(3)N = O does not (R = alkyl group) ?

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  3. Explain why NH(3) is basic while BiH(3) is only feebly basic ?

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  4. Nitrogen exist diatomic molecule and phosphorus as P(4). Why ?

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  5. Why does nitrogen show catenation properties less than phosphorus ?

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  6. Give reasons for the following : (i) Nitric oxide becomes brown when...

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  7. What happens when PCl(5) is heated?

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  8. Write a balanced equation for the hydrolytic reaction of PCl(5) with h...

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  9. Are all the five bonds of PCl(5) equivalent ? Justify your answer.

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  10. For the manufacture of Ammonia by Haber's process, write the equation ...

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  11. How does ammonia reacts with a solution of Cu^(2+)?

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  12. Give the disproportionation reaction of H(3)PO(3).

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  13. Complete the following chemical equations : (i) Ca(3)P(2)+H(2)Orarr ...

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  14. Arrange the following in the order of property indicated against each ...

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  15. Complete the following equations : (i) P(4)+H(2)Orarr (ii) XeF(4)+...

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  16. Complete the following equations : (i) Ag+PCl(5)rarr (ii) CaF(2)+H...

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  17. Explain the following : (i) NO(2) readily forms a dimer. (ii) BiCl...

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  18. Explain the following facts giving appropriate reason in each case : ...

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  19. Draw the structures of white phosphorus and red phosphorus. Which one ...

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  20. Complete the following chemical reaction equations : (i) I(2)+unders...

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