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Why are pentahalides of P, As, Sb and Bi...

Why are pentahalides of P, As, Sb and Bi more covalent than their trihalides ?

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The central atom in higher oxidation state has greater polarizing power which increases the covalent character of the bond between central atom and the surrounding atoms.
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KUMAR PRAKASHAN-THE P-BLOCK ELEMENTS -SECTION-B (INTEXT QUESTIONS AND ANSWERS)
  1. Why are pentahalides of P, As, Sb and Bi more covalent than their trih...

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  2. Why is BiH3 the strongest reducing agent amongst all the hydrides of G...

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  3. Why is N2 less reactive at room temperature ?

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  4. Mention the conditions required to maximise the yield of ammonia.

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  5. How does ammonia react with a solution of Cu^(2+)?

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  6. What is the covalence of nitrogen in N(2)O(5) ?

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  7. (a) Bond angle in PH4 is higher than that in PH3. Why ? (b) What is ...

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  8. What happens when white phosphorus is heated with concentrated NaOH so...

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  9. What happens when PCl5 is heated ?

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  10. Write a balanced equation for the reaction of PCl5 with water.

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  11. What is the basicity of H(3)PO(3) is heated?

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  12. What happens when H3PO(3) is heated ?

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  13. List the important sources of sulphur.

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  14. Write the order of thermal stability of the hydrides of Group-16 eleme...

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  15. Why is H2O a liquid and H2S a gas ?

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  16. Which of the following does not react with oxygen directly ? Zn, Ti, P...

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  17. Complete the following reactions : (i) C(2)H(4) + O(2) to (ii) 4Al...

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  18. Why does O(3) act as a powerful oxidising agent ?

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  19. How is O(3) estimated quantitatively ?

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  20. What happens when sulphur dioxide is passed through an aqueous solutio...

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