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Which of the compounds will react faster...

Which of the compounds will react faster in `S_(N)1` reaction with the `""^(-)OH` ion ?
`CH_(3)-CH_(2)-Cl` OR `C_(6)H_(5)-CH_(2)-Cl`

Text Solution

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`C_(6)H_(5)-CH_(2)-Cl` will react faster in `S_(N)1` because the reaction will pass through more stable benzyl carbocation `(C_(6)H_(5)overset(+)(C )H_(2))` intermediate.
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KUMAR PRAKASHAN-HALOALKANES AND HALOARENES-SECTION - D NCERT EXEMPLAR SOLUTION (Short Answer Type Questions)
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  2. Out of o - and p - dibromobenzene which one has higher melting point a...

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  3. Which of the compounds will react faster in S(N)1 reaction with the ""...

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  4. Why iodoform has appreciable antiseptic property ?

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  5. Haloarenes are less reactive than haloalkanes and haloalkenes. Explain...

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  6. Discuss the role of Lewis acids in the preparation of aryl bromides an...

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  7. Which of the following compounds (i) and (ii) will not react with a mi...

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  8. Which of the products will be major product in the reaction given belo...

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  9. Why is the solubiliuty of haloalkanes in water very low ?

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  10. Draw other resonance structures related to the following structure and...

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  11. Classify the following compounds as primary, secondary and tertiary ha...

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  12. Compound 'A' with molecular formula C(4)H(9)Br is treated with aq. KOH...

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  13. Write the structures and names of the compounds formed when compound '...

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  14. Identify the products A and B formed in the following reaction : C...

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  15. Which of the following compounds will have the highest melting point a...

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  16. Write down the structure and IUPAC name for neo-pentylbromide.

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  17. A hydrocarbon of molecular mass 72 g mol^(-1) gives a single monochlor...

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  18. Name of the alkene which will yield/chloro-1-methylcyclohexane by its ...

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  19. Which of the following haloakanes reacts with aqueous KOH most easily ...

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  20. Why can aryl halieds not be prepared by reaction of phenol with HCl in...

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