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An organic compound A(C4 H7 C(13)) yield...

An organic compound `A(C_4 H_7 C_(13))` yields(B) when treated with aq. KOH. (B) upon treatment with `C_2 H_5 OH` in presence of acid gave (C) which upon reducing with `LiAIH_4` gave (D) and (E). (B) upon treatment with `NH_3` followed by heating with `P_4 O_(10)` and subsequent hydrolysis gives back(B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode.
Compound (B) can also be obtained by

A

catalysed `(Hg SO_4)` hydration of 1-butone

B

reduction of `CH_3-overset(OH)overset(|)CH-overset(O)overset(||)COC_2 H_5` with `LiAIH_4`

C

oxidative cleavage of 4-methyl-2-pentene

D

All the above

Text Solution

Verified by Experts

The correct Answer is:
C

oxidative cleavager of 4-methyl 2-pentene gives acetic acid and isobutylic acid (B) `H_3 C - HC= underset(CH_3)underset(|)CH-CH- CH_3 underset(H^+)overset(KMnO_4)to H_3 C - COOH + underset(CH_3)underset(|)H_3 C - CH-underset(B)underset()(COOH)`
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Knowledge Check

  • An organic compound A(C_4 H_7 C_(13)) yields (B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back (B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. Compound (D) and (E) respectively are

    A
    `CH_3 CH_2 CH_2 OH, C_2 H_5 OH`
    B
    `CH_3 - underset(CH_3)underset(|)CHCH_2 OH, C_2 H_5 OH`
    C
    `CH_3CH_2 CH_2 CH_2 OH,C_2 H_5 OH`
    D
    `CH_3-underset(CH_3)underset(|)CHCH_2 - OCH_3- CH_3OH`

  • An organic compound A(C_4 H_7 C_(13)) yields(B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back(B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. Compound (D) and (E) respectively are

    A
    `CH_3 CH_2 CH_2 OH , C_2 H_5 OH`
    B
    `CH_3 -underset(CH_3)underset(|)CHCH_2 OH, C_2 H_5 OH`
    C
    `CH_3CH_2 CH_2 CH_2 OH, C_2 H_5 OH`
    D
    `CH_3 - underset(CH_3)underset(|)CHCH_(2_@)-OCH_3, CH_3 OH`

  • An organic compound A(C_4 H_7 C_(13)) yields (B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back (B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. The IUPAC name of compound (A) is

    A
    1,1,2-trichlorobutane
    B
    1,2,2-trichlorobutane
    C
    1,1,2-trichloro-2-methylpropane
    D
    1,1,1-trichloro-2-methylpropane

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