The Killingham diagram for sing, magnesium and carbon converting into corresponding oxides is shown below :
To make the following reduction process spontaneous, temperature should be
The Killingham diagram for sing, magnesium and carbon converting into corresponding oxides is shown below :
To make the following reduction process spontaneous, temperature should be
To make the following reduction process spontaneous, temperature should be
A
`1000^(@)C`
B
`gt1100^(@)C`
C
`lt5000^(@)C`
D
`lt1000^(@)C`
Text Solution
Verified by Experts
The correct Answer is:
B
From Ellinghams diagram `gt 1100^(@)C`
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For a spontaneous reaction, the free energy change must be negative. DeltaG=DeltaH-TDeltaS is the enthalpy change during the reaction. T is absolute temperature, and AS is the change in entropy during the reaction. Consider a reaction such as the formation ofan oxide . M+O_(2) MO Dloxygen is used wp in the course of this reaction. Gases have a more random structure (less ordered) than liquid or solids consequently gases have a higher entropy than liquids and solids, in this reaction (entropy or randomness) decreases, hence is negative. Thus, the temperature is raised the DeltaS becomes more negative. Since, TDeltaS is subtracted in the equation, then SG becomes less negative. Thus, the free energy changes increases with the increase in temperature. The free energy changes that occur when one mole of common reactant in this case dioxygen) is we may e plotted graphically against temperature for a number of reactions of metals to their oxides. The following plot is called an Ellingham diagram for metal oxide. Understanding of Ellingham diagram is extremely important for the efficient extraction of metals. As per the Ellingham diagram of oxides which of the following conclusion is true?
For a spontaneous reaction, the free energy change must be negative. DeltaG=DeltaH-TDeltaS is the enthalpy change during the reaction. T is absolute temperature, and AS is the change in entropy during the reaction. Consider a reaction such as the formation ofan oxide . M+O_(2) MO Dloxygen is used wp in the course of this reaction. Gases have a more random structure (less ordered) than liquid or solids consequently gases have a higher entropy than liquids and solids, in this reaction (entropy or randomness) decreases, hence is negative. Thus, the temperature is raised the DeltaS becomes more negative. Since, TDeltaS is subtracted in the equation, then SG becomes less negative. Thus, the free energy changes increases with the increase in temperature. The free energy changes that occur when one mole of common reactant in this case dioxygen) is we may e plotted graphically against temperature for a number of reactions of metals to their oxides. The following plot is called an Ellingham diagram for metal oxide. Understanding of Ellingham diagram is extremely important for the efficient extraction of metals. Which of the following elements can be prepared by heating the oxide above 400^(@)C ?
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For a spontaneous reaction, the free energy change must be negative. DeltaG=DeltaH-TDeltaS is the enthalpy change during the reaction. T is absolute temperature, and AS is the change in entropy during the reaction. Consider a reaction such as the formation ofan oxide . M+O_(2) MO Dloxygen is used wp in the course of this reaction. Gases have a more random structure (less ordered) than liquid or solids consequently gases have a higher entropy than liquids and solids, in this reaction (entropy or randomness) decreases, hence is negative. Thus, the temperature is raised the DeltaS becomes more negative. Since, TDeltaS is subtracted in the equation, then SG becomes less negative. Thus, the free energy changes increases with the increase in temperature. The free energy changes that occur when one mole of common reactant in this case dioxygen) is we may e plotted graphically against temperature for a number of reactions of metals to their oxides. The following plot is called an Ellingham diagram for metal oxide. Understanding of Ellingham diagram is extremely important for the efficient extraction of metals. Free energy change of Hg and Mg for the convertion to oxides the slope of DeltaG . T has been changed above the boiling points of the given metal because
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Electrolysis is the process in which electrical energy is converted to chemical energy. In electrolyte cell, oxidation takes place at anode and reduction at cathode. Electrode process depends on the electrode taken for electrolysis. Amount of substance liberated at an electrode is directly proportionation to the amount of charge passed through it. The mass of substance liberated at electrode is calculate using the following realation : m=(itE)/(96500) Here, E represent the equivalent mass and 96500 C is called the faraday constant. Faraday (96500 C) is the charge of 1 mole electron i.e., 6.023 xx 10^(23) electrons, it is used to liberate on gram equivalent of the substance. Calculate the volume of gas liberated at the anode at STP during the electrolysis of a CuSO_4 solution by a current of 1 A passed for 16 minutes and 5 seconds.