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BCl(3) doesnot exist as dimer but BH(3) ...

`BCl_(3)` doesnot exist as dimer but `BH_(3)` exist as dimer `(B_(2)H_(6))` because

A

chlorine is more electronagative than hydrogen

B

there is `p pi- d pi` back bonding in `BCl_(3)` but `BH_(3)` doesnot contain such multiple bonds

C

large size chlorine atom donot fir in between small boran atoms where as small sized hydrogen atom get fitted in between boran atoms

D

none of the above

Text Solution

Verified by Experts

The correct Answer is:
C

Small sized boran atom cannot coordinate to four large size chlorine atims.
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  2. AlCl(3) exist as dimer because

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  16. Boran forms a number of hydrides having the general formulae BnH(n+4) ...

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  17. Boran forms a number of hydrides having the general formulae BnH(n+4) ...

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  18. Boran forms a number of hydrides having the general formulae BnH(n+4) ...

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  19. Boran forms a number of hydrides having the general formulae BnH(n+4) ...

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