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An alcohol (A) on dehydration gives (B) ...

An alcohol (A) on dehydration gives (B) which on ozonolysis gives two products C & D (D) gives positive iodoform test and on heating with dilute alkali gives `alpha . beta `-unsaturated carbonyl compound (E) which does not gives positive iodoform test. (C) on oxidation gives a mono basic acid (F) Ag salt of (F) contains 59.6% Ag. Oxime of (D) contains 16.09% nitrogen.
the structure of (A) is

A

`CH_3(CH_2)_2 C(CH_3)(OH)CH_2 CH_3`

B

`CH_3CH_2 CH(OH) CH (CH_3)C_2 H_5`

C

`CH_3 CH_2 C (CH_3)(OH) CH_2 CH_3`

D

`CH_3CH_2 CH (OH) (CH _3)_2`

Text Solution

Verified by Experts

The correct Answer is:
D

On zonolysis gives 2 products ` therefore ` By vertification , it is clear that
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AAKASH SERIES-ALDEHYDES AND KETONES-PRACTICE SHEET-2
  1. The major product in the following reaction is

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  2. the possible products are

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  3. In which of the following reation, the product is a hydrocarbon

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  4. In which of the following reactions, the product is racemic mixture

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  5. the possible products are

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  6. Identify the correct reagent(s) to distinguish between pairs of compou...

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  7. An alcohol (A) on dehydration gives (B) which on ozonolysis gives two ...

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  8. An alcohol (A) on dehydration gives (B) which on ozonolysis gives two ...

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  9. An alcohol (A) on dehydration gives (B) which on ozonolysis gives two ...

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  10. Compounds A(C9 H8 O3) on reduction with Zn-Hg&HCI gave a carboxylic ac...

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  11. Compounds A(C9 H8 O3) on reduction with Zn-Hg&HCI gave a carboxylic ac...

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  12. Compounds A(C9 H8 O3) on reduction with Zn-Hg&HCI gave a carboxylic ac...

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  13. Match the following columns

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  14. Match the following columns

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  15. The number of a bonds in the product formed in acid catlysed reaction ...

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  16. When acetone is treated with ""^(18)O labeled water and isolating the ...

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  17. How many compounds given below are not reduced by catalytic hydrogenat...

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  18. Total number of ketones with molecular formula C5 H(10) O including st...

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  19. Number of aldehydes isomers of butanone is

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  20. Total number of steriosomers possible for 2,3-dichlorobutanal is

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