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Coordination number of Cr is 6. A comple...

Coordination number of Cr is 6. A complete entity with `C_(2)O_(4)^(-2)`, en superoxide as ligands is `[Cr(C_(2)O_(4))_(x)(en)_(y)(O_(2))_(z)]^(+)`. The ratio of x: y : z is

A

`1:1:2`

B

`1:1:1`

C

`1:2:3`

D

`2:1:1`

Text Solution

Verified by Experts

The correct Answer is:
A

(en) and (ox) are bidentate ligands `(O_(2)^(-))` is monodentate by verification `1xx2+1xx2+2xx2=6`
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AAKASH SERIES-CO-ORDINATION COMPOUNDS-LEVEL-II LECTURE SHEET EXERCISE-I (Single & One or more than One Correct Answers )
  1. Which of the following statement(s) is/are correct?

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  2. The d-orbitals involved in sp^(3)d^(2) or d^(2)sp^(3) hybridisation of...

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  3. Coordination number of Cr is 6. A complete entity with C(2)O(4)^(-2), ...

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  4. Which of the following statement(s) is (are) correct?

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  5. For [Fe(CN)(6)]^(4-).[Ni(CN)(4)]^(2-)and[Ni(CO)(4)]. Correct statement

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  6. Which have octahedral shape (d^(2)sp^(3)) hybridisation of central ato...

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  7. Which possesses tetrahedral shape (sp^(3)- hybridisation of central at...

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  8. Which of the following complexes is a chelate ?

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  9. A complex shown below can exhibit :

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  10. Which of the following compounds can exhibit geometrical isomerism?

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  11. Which of the following isomerisms are exhibited by [Cr(NH(3))(2)(OH)(2...

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  12. Which of the following statements is not true about the complex ion [C...

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  13. Which of the following statement(s) is/are incorrect?

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  14. Which of the following statements is/are true ?

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  15. Which of the following statement is true about the complex [CrCl(3)(OH...

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  16. Which of the following pairs show coordination isomerism ?

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  17. A metal comples having composition Cr(NH(3))(4)CI(2)Br has been isolat...

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  18. In poly nuclear metal carbonyls, the hybridisation of 'C' in terminal ...

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  19. Which is high spin complex :

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  20. A d-block element forms octahedral complex but its magnetic moment rem...

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