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Which of the following statement(s) is/a...

Which of the following statement(s) is/are incorrect?

A

In `[CoBrCl(en)_(2)]^(+)` geometrical isomerism exists, while optical isomerism does not exist

B

IUPAC name of `K_(2)[Cr(CN)_(2)O_(2)(O_(2))(H_(2)O)]` is Potassium aquadicyanosuperoxo peroxo chromate(III)

C

There are 3 geometrical and 15 stereoisomers possible for `[Pt(NO_(2))(NH_(3))(NH_(2)OH)(py)]^(+)and[PtBrClI(NO_(2))(NH_(3))(py)]` respectively

D

cis and transforms are not diastereomers to each other.

Text Solution

Verified by Experts

The correct Answer is:
A, B, C, D

Its cis isomer is optically active.
b) Sequence is .peroxo superoxo..
c) Sequence planar [M a b c d] will have 3 geometrical isomers octahedral [Mabc d e f] will have 15 geometrical isomers, each one being chiral.
d) Non-mirror images are diastereomers.
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AAKASH SERIES-CO-ORDINATION COMPOUNDS-LEVEL-II LECTURE SHEET EXERCISE-I (Single & One or more than One Correct Answers )
  1. Which of the following statement(s) is (are) correct?

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  2. For [Fe(CN)(6)]^(4-).[Ni(CN)(4)]^(2-)and[Ni(CO)(4)]. Correct statement

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  3. Which have octahedral shape (d^(2)sp^(3)) hybridisation of central ato...

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  4. Which possesses tetrahedral shape (sp^(3)- hybridisation of central at...

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  5. Which of the following complexes is a chelate ?

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  6. A complex shown below can exhibit :

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  7. Which of the following compounds can exhibit geometrical isomerism?

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  8. Which of the following isomerisms are exhibited by [Cr(NH(3))(2)(OH)(2...

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  9. Which of the following statements is not true about the complex ion [C...

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  10. Which of the following statement(s) is/are incorrect?

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  11. Which of the following statements is/are true ?

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  12. Which of the following statement is true about the complex [CrCl(3)(OH...

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  13. Which of the following pairs show coordination isomerism ?

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  14. A metal comples having composition Cr(NH(3))(4)CI(2)Br has been isolat...

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  15. In poly nuclear metal carbonyls, the hybridisation of 'C' in terminal ...

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  16. Which is high spin complex :

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  17. A d-block element forms octahedral complex but its magnetic moment rem...

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  18. For which of the following d^(n) configuration of octahedral complex(e...

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  19. Select the correct statement

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  20. Which one of the following statement (s) is/are false ?

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