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A d-block element forms octahedral compl...

A d-block element forms octahedral complex but its magnetic moment remains same either in strong field or in weak field ligand. Which of the following is/are correct ?

A

Element always forms colourless compound

B

Number of electrons in `t_(2_(g))` orbitals are higher than in `e_(g)` orbitals

C

It can have either `d^(3)` or `d^(8)` configuration

D

It can have either `d^(7)` or `d^(8)` configuration

Text Solution

Verified by Experts

The correct Answer is:
B, C

* For `d^(3)` configuration :
In strong ligand field : `t_(2)^(3)eg^(0)` : In weak ligand field `:t_(2g)^(3)eg^(0)`
* For `d^(8)` configuration :
In strong ligand field : `t_(2g)^(6)eg^(2)` , In weak ligand field : `t_(2g)^(6)eg^(2)`
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AAKASH SERIES-CO-ORDINATION COMPOUNDS-LEVEL-II LECTURE SHEET EXERCISE-I (Single & One or more than One Correct Answers )
  1. Which of the following statement(s) is (are) correct?

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  2. For [Fe(CN)(6)]^(4-).[Ni(CN)(4)]^(2-)and[Ni(CO)(4)]. Correct statement

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  3. Which have octahedral shape (d^(2)sp^(3)) hybridisation of central ato...

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  4. Which possesses tetrahedral shape (sp^(3)- hybridisation of central at...

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  5. Which of the following complexes is a chelate ?

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  6. A complex shown below can exhibit :

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  7. Which of the following compounds can exhibit geometrical isomerism?

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  8. Which of the following isomerisms are exhibited by [Cr(NH(3))(2)(OH)(2...

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  9. Which of the following statements is not true about the complex ion [C...

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  10. Which of the following statement(s) is/are incorrect?

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  11. Which of the following statements is/are true ?

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  12. Which of the following statement is true about the complex [CrCl(3)(OH...

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  13. Which of the following pairs show coordination isomerism ?

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  14. A metal comples having composition Cr(NH(3))(4)CI(2)Br has been isolat...

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  15. In poly nuclear metal carbonyls, the hybridisation of 'C' in terminal ...

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  16. Which is high spin complex :

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  17. A d-block element forms octahedral complex but its magnetic moment rem...

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  18. For which of the following d^(n) configuration of octahedral complex(e...

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  19. Select the correct statement

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  20. Which one of the following statement (s) is/are false ?

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