Home
Class 12
CHEMISTRY
underset((aq))Co^(2+)+underset((aq))SCN^...

`underset((aq))Co^(2+)+underset((aq))SCN^(-)to` complex (a)
`underset((aq))Ni^(2+)+dmgoverset(NH4OH)to` complex (y)
The CN of Co, Ni in comp,exes (x) & (y) are four
The geometry of complex (x) & (y) are respectively

A

Tetrahedral & square planar

B

both tetrahedral

C

Square planar, tetrahedral

D

both square planar

Text Solution

Verified by Experts

The correct Answer is:
B

`X=[Co(SCN)_(4)]^(2-)`
`Y=[Ni(dmg)_(2)]`
Both of them axetetrahedral and `sp^(3)` hybridised.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE SHEET - 3 ( Linked Comprehension type questions Passage - II:)|3 Videos
  • CO-ORDINATION COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE SHEET - 3 ( Match the following questions)|2 Videos
  • CO-ORDINATION COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE SHEET - 3 (Single or more than one option questions)|16 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    AAKASH SERIES|Exercise PRACTICE SHEET - 2 (PRACTICE SHEET -2 (INTEGER ANSWER TYPE QUESTIONS))|7 Videos
  • COMPLEX COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE EXERCISE|45 Videos

Similar Questions

Explore conceptually related problems

H_3 C CH_2 CO_2 H underset(Delta)overset(NH_3)to X underset(Delta)overset(-OH)toY. What are X and Y ?

CH_3 CH_2 COOH underset("Red P")overset(Br_2)to X underset("alcohol")overset(NH_3)to Y Y in the reaction is

Knowledge Check

  • underset((aq))Co^(2+)+underset((aq))SCN^(-)to complex (a) underset((aq))Ni^(2+)+dmgoverset(NH4OH)to complex (y) The CN of Co, Ni in comp,exes (x) & (y) are four The geometry of [NiCl_(4)]^(-2)and[NiPph_(3))_(2)Cl_(2)] are

    A
    tetrahedral & square planar respectively
    B
    both tetrahedral
    C
    both square planar
    D
    square planar & tetrahedral respectively
  • underset((aq))Co^(2+)+underset((aq))SCN^(-)to complex (a) underset((aq))Ni^(2+)+dmgoverset(NH4OH)to complex (y) The CN of Co, Ni in comp,exes (x) & (y) are four Select the correct statements for the complexes 'x' and 'y'

    A
    ‘x' in paramagnetic with two unpaired `e^(-)`
    B
    y' is diamagnetic with intermolecular H-bonding
    C
    x' is paramagnetic with 3 unpaired e" and 'y' is diamagnetic
    D
    x' and 'y' both are diamagnetic
  • Sucrose underset ( H^(-)) overset (H_2O) to Y and X. The total no of optical isomers possible for Y and X are

    A
    `a`. 16
    B
    `b`. 8
    C
    `c`. 32
    D
    `d`. 24
  • Similar Questions

    Explore conceptually related problems

    Geometrical shapes of the complexes formed by the reaction of Ni^(2+) with Cl^(-), CN^(-) and H_2O , respectively, are

    C_2H_4 underset( AlCl_3) overset( HCl) to A overset( KOH (aq.) ) to B underset( 140^(@) C ) overset( Conc. H_2SO_4) to C What is the final product?

    The geometry and magnetic behavior of the complex [Ni(CO)_4] are

    CH_3 CHO +NH_2 OH to X underset(-H_2 O) to Y The number of sigma bonds pi bonds and lone pairs of electrons in the compound 'Y' are respectively

    C_6H_5CH_2OH overset(HBr)to X overset(KCN)to Y Y underset(Delta)overset(H_3O^(+))to Z . What are X, Y and Z ?