Home
Class 12
CHEMISTRY
A complex PtCI(4).5NH(3) shows a molar c...

A complex `PtCI_(4).5NH_(3)` shows a molar conductance of `402 ohm^(-1) cm^(-2) mol^(-1)` in water and precipitate 3 mole of AgCl with `AgNO_(3)`. The formula of the complex is

A

`[Pt(NH_(3))_(6)]Cl_(4)`

B

`[Pt(NH_(3))_(5)Cl]Cl_(3)`

C

`[Pt(NH_(3))_(4)Cl_(2)]Cl_(2)`

D

`[Pt(NH_(3))_(3)Cl_(3)]Cl`

Text Solution

Verified by Experts

Based on `PtCl_(4).5NH_(3),CN` of Pt is 6.
To give 3 mole of AgCl with `AgNO_(3),3Cl^(-)` ions must be present in ionization sphere of the complex. `:.` Formula of complex `[Pt(NH_(3))_(5)Cl]Cl_(3)`.
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE SHEET - 5 ( Linked Comprehension type questions Passage : 1 :)|3 Videos

  • CO-ORDINATION COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE SHEET - 5 ( Linked Comprehension type questions Passage : I I:)|3 Videos

  • CO-ORDINATION COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE SHEET - 4 (Integer answer type Questions )|6 Videos

  • CHEMISTRY IN EVERYDAY LIFE

    AAKASH SERIES|Exercise PRACTICE SHEET - 2 (PRACTICE SHEET -2 (INTEGER ANSWER TYPE QUESTIONS))|7 Videos

  • COMPLEX COMPOUNDS

    AAKASH SERIES|Exercise PRACTICE EXERCISE|45 Videos

Similar Questions

Explore conceptually related problems

How many moles of AgCl is precipitated when I mole of CoCl_(3) is treated with AgNO_(3) solution?

Specific conductance of 0.1 M Nitric acid is 6.3 xx 10^(-2) "ohm"^(-1) cm^(-1) "mol"^(-1) The molar conductance of the solution is

The complex compound which does not give precipitate with AgNO_(3) solution is

A complex compound of cobalt contains five NH_(3) molecules. One nitro group and two chloride ions for one Co atom. One mole of this compound produces three mole ions in aq. solution. On reacting with excess of AgNO_(3) solution, two moles of AgCl get precipitated. The formula of the complex compound is

The complex ion [Cu(NH_(3))_(4)]^(2+) has :

One mole of the complex Co(NH_(3))_(5)Cl_(3) gives 3 moles o f ions on dissolution in water. One mole of he same complex reacts with two moles of AgNO_(3) solution to yield two moles of AgCl(s). The structure of the complex is

Assertion: The complex [Co(NH_3)_3Cl_3] gives no precipitate with AgNO_3 solution Reason: The given complex is non-ionizable

A coordination compound is made of Co^(3+),NH_(3)andCl^(-),0.1M solution of this complex when treated with excess silver nitrate gaye no precipitate. The formula of the complex and secondary valency of metal are respectively.