Home
Class 12
CHEMISTRY
In a solid ,oxide (O^(2-)) ions are arr...

In a solid ,oxide `(O^(2-))` ions are arranged in ccp, cations `(A^(3+))` occupy one -sixth of tetrahedral void and cations `(B^(3+))` occupy one -third of the octahedral voids . What is the formula of the compound?

Text Solution

Verified by Experts

Number of oxide ions forming ccp=4
(Occupy 8 corners and 6 faces centres )
Number of Tetrahedral voids =8
Number of octahedral voids =4
Number of cations A occupying Tetrahedral voids =`8/6`
Number of cations B occupying Octahedral voids =`4/3`
`A:B:O^(-2)`
`8/6:4/3:4`
8:8:24
`therefore` 1:1:3
And formula of compound is `ABO_3`
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    AAKASH INSTITUTE|Exercise Try Yourself|56 Videos
  • THE SOLID STATE

    AAKASH INSTITUTE|Exercise ASSIGNMENT SECTION-A (OBJECTIVE)|50 Videos
  • THE S-BLOCK ELEMENTS

    AAKASH INSTITUTE|Exercise Assignment (Section-J)|10 Videos
  • THERMODYNAMICS

    AAKASH INSTITUTE|Exercise ASSIGNMENT (Section -D) Assertion-Reason Type Questions|15 Videos

Similar Questions

Explore conceptually related problems

In a solid, oxide ions are arranged in ccp. Cations 'A' occupy one - sixth of the tetrahedral voids and cations 'B' occupy one - third of the octahedral voids. Which of the following is the correct formula of the oxide?

In a compound,oxide ions are arranged in cubic close packing arrangement. Cations A occupy one-sixth of the tetrahdral voids and cations B occupy one-third of the octahedral voids. The formula of the compound is

In a solid, oxide ions are arrnged in ccp, cations A occupy A occupy (1/8)^th of the tetrahedral voids and cation B occupy (1/4)^(th) of the octahedral voids. The formula of the compound is:

In certain solid, the oxide ions are arranged in ccp. Cations A occupy (1)/(6) of the tetrahedral voids and cations B occupy one third of the octahedral voids. The probable formula of the compound is

In solid, oxide ions are arranged in ccp. One sixth of the tetrahedral voids are occupied by the cations (A) while one third of the octahedral voids, are occupied by the cations (B). What is the formula of the compound ?

AAKASH INSTITUTE-THE SOLID STATE -Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)
  1. In a solid ,oxide (O^(2-)) ions are arranged in ccp, cations (A^(3+)...

    Text Solution

    |

  2. A : In NaCl structure, the interionic distance is a/2 (a = Unit cell e...

    Text Solution

    |

  3. A : The co - ordination number of CaF(2) is 8 : 4. R : Ca^(2+) ion...

    Text Solution

    |

  4. A : The number of spheres are equal to the number of octahedral voids ...

    Text Solution

    |

  5. A : In Schottky defect, density of crystal decreases. R : Equal nu...

    Text Solution

    |

  6. A : If a tetrad axis is passed through the unit cell of NaCl and all i...

    Text Solution

    |

  7. A : A particle at the corner of CCP unit cell has (1)/(8)th of its con...

    Text Solution

    |

  8. A : Glass belongs to the category of covalent network solid. R : U...

    Text Solution

    |

  9. A : NaCl shows Schottky defect at room temperature. R : NaCl shows...

    Text Solution

    |

  10. A : Fe(3)O(4) is ferrimagnetic at room temperature but becomes paramag...

    Text Solution

    |

  11. A : In molecular solids the lattice points are occupied by the atoms o...

    Text Solution

    |

  12. A : Silicon is insulator at 0 K but semiconductor at room temperature....

    Text Solution

    |

  13. A : Amorphous solids are isotropic. R : Amorphous solids are not rig...

    Text Solution

    |

  14. A : In NaCl coordination number of Cl^(-) ion is 6 but in CsCl coordin...

    Text Solution

    |

  15. A : All crystals of same substance possess the same elements of symmet...

    Text Solution

    |

  16. A : AgBr shows both Schottky and Frenkel defect. R : AgBr is a cry...

    Text Solution

    |

  17. A : Number of carbon atoms per unit cell in diamond is 8. R : The ...

    Text Solution

    |

  18. A : The coordination number of ionic compound depends upon radius rati...

    Text Solution

    |

  19. A : Number of rectangular plane in a cubic crystal is 3. R : Recta...

    Text Solution

    |

  20. A : ccp is more efficient than hcp. R : Packing fraction is differe...

    Text Solution

    |

  21. A : Coordination number of both Na^(+) and Cl^(-) NaCl is 6. R : Se...

    Text Solution

    |