Home
Class 12
CHEMISTRY
Find out of 1st,2nd and 3rd coordination...

Find out of 1st,2nd and 3rd coordination number for an atom located at the corner in a simple cubic unit cell

Text Solution

Verified by Experts

Let the desired atoms is A
(i)1st C.N.
1st nearest neighbours are at a distance a (edge length ) from point A.So, 1st C.N.=6

(ii)2nd C.N.
2nd nearest neighbours are at a distance `asqrt2` from point A, as shown . For one plane (let X-Y) `2nd` nearest neighbrous =4

For three planes (XY,YZ and ZX), 2nd C.N. =12
(iii)3rd C.N. :
3rd nearest neighbours are at a distance `asqrt3` from point A , i.e., at the other end of body diagonals (as shown ) .

A is contributed in eight cubes . So, 3rd C.N.=8
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    AAKASH INSTITUTE|Exercise Try Yourself|56 Videos
  • THE SOLID STATE

    AAKASH INSTITUTE|Exercise ASSIGNMENT SECTION-A (OBJECTIVE)|50 Videos
  • THE S-BLOCK ELEMENTS

    AAKASH INSTITUTE|Exercise Assignment (Section-J)|10 Videos
  • THERMODYNAMICS

    AAKASH INSTITUTE|Exercise ASSIGNMENT (Section -D) Assertion-Reason Type Questions|15 Videos

Similar Questions

Explore conceptually related problems

How many atoms are present in a simple cubic unit cell?

The coordination number for an atom in a primitive cubic unit cell is :

The coordination number of each atom in simple cubic structure is

The coordination number of each atom in body centered cubic unit cell is

AAKASH INSTITUTE-THE SOLID STATE -Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)
  1. Find out of 1st,2nd and 3rd coordination number for an atom located at...

    Text Solution

    |

  2. A : In NaCl structure, the interionic distance is a/2 (a = Unit cell e...

    Text Solution

    |

  3. A : The co - ordination number of CaF(2) is 8 : 4. R : Ca^(2+) ion...

    Text Solution

    |

  4. A : The number of spheres are equal to the number of octahedral voids ...

    Text Solution

    |

  5. A : In Schottky defect, density of crystal decreases. R : Equal nu...

    Text Solution

    |

  6. A : If a tetrad axis is passed through the unit cell of NaCl and all i...

    Text Solution

    |

  7. A : A particle at the corner of CCP unit cell has (1)/(8)th of its con...

    Text Solution

    |

  8. A : Glass belongs to the category of covalent network solid. R : U...

    Text Solution

    |

  9. A : NaCl shows Schottky defect at room temperature. R : NaCl shows...

    Text Solution

    |

  10. A : Fe(3)O(4) is ferrimagnetic at room temperature but becomes paramag...

    Text Solution

    |

  11. A : In molecular solids the lattice points are occupied by the atoms o...

    Text Solution

    |

  12. A : Silicon is insulator at 0 K but semiconductor at room temperature....

    Text Solution

    |

  13. A : Amorphous solids are isotropic. R : Amorphous solids are not rig...

    Text Solution

    |

  14. A : In NaCl coordination number of Cl^(-) ion is 6 but in CsCl coordin...

    Text Solution

    |

  15. A : All crystals of same substance possess the same elements of symmet...

    Text Solution

    |

  16. A : AgBr shows both Schottky and Frenkel defect. R : AgBr is a cry...

    Text Solution

    |

  17. A : Number of carbon atoms per unit cell in diamond is 8. R : The ...

    Text Solution

    |

  18. A : The coordination number of ionic compound depends upon radius rati...

    Text Solution

    |

  19. A : Number of rectangular plane in a cubic crystal is 3. R : Recta...

    Text Solution

    |

  20. A : ccp is more efficient than hcp. R : Packing fraction is differe...

    Text Solution

    |

  21. A : Coordination number of both Na^(+) and Cl^(-) NaCl is 6. R : Se...

    Text Solution

    |