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Statement-1:In a hexagonal close packin...

Statement-1:In a hexagonal close packing , third layer is identical to first layer.
Statement-2: In a primitive unit-cell, the third nearest neighbours of an atom located at a corner are at the other end of face-diagonal.
Statement-3: If the radius of cation is nearly equal to radius of anions, then most favourable arrangement is BCC.

A

T T T

B

F F T

C

T F T

D

T T F

Text Solution

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The correct Answer is:
C
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Statement -1 In HCP structure the contribution of hexagonal face corner per atom is 1/12 Statement -2 it is shared by 6 different unit cells

All real structures are three dimensional structures. They can be obtained by stacking two dimensional layers one above the other while placing the second square dose packed layer above the first we follow the same rule that was followed when one row was placed adjacent to the other. The second layer is placed over the first layer such that the spheres of the upper layer are exactly above there of the first layer. In his arrangement spheres of both the layers are perfectly aligned horizontally as well as vertically. A metallic element crystallise into a lattice having a ABC ABC pattern and packing of spheres leaves out voids in the lattice. Which of the following statements is not true for unit cell?

All real structures are three dimensional structures. They can be obtained by stacking two dimensional layers one above the other while placing the second square dose packed layer above the first we follow the same rule that was followed when one row was placed adjacent to the other. The second layer is placed over the first layer such that the spheres of the upper layer are exactly above there of the first layer. In his arrangement spheres of both the layers are perfectly aligned horizontally as well as vertically. A metallic element crystallise into a lattice having a ABC ABC pattern and packing of spheres leaves out voids in the lattice. What is the total volume of atoms in a face centred cubic unit cell of a metal? (r is atomic radius).

In hexagonal system of crystals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are regular hexagons and three atoms are sandwiched in between them. A space -filling model of this structure, called hexagonal close-packed (HCP), is consituted of a sphere on a flat surface surrouneded in the same plane by six identical spheres as closely possible. Three sphere are then palces over the first layer so that they touch each other and represent second layer is covered with third layer that is identical to the bottom layer in relative position. Assume radius of enery sphere to be r. The number of atoms in the HPC unit cell is :