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Assertion: Elevation in boiling point is...

Assertion: Elevation in boiling point is inversely proportional to lowering of vapour pressure for dilute solutions.
Reason: Lowering of vapour pressure is directly proportional to mole fraction of solvent.

A

Both Assertion and Reason are true and Reason is the correct explanation of Assertion

B

Both Assertion and Reason are true and Reason is not the correct explanation of Assertion

C

Assertion is true but Reason is false

D

Both Assertion and Reason are false

Text Solution

Verified by Experts

The correct Answer is:
D
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Assertion : Vapour pressure of 0.5M sugar solution is more than 0.5M KCl solution Reason: Lowering of vapour pressure is directly proportional to the number of particles present in the solution

At a given temperature (a) Vapour pressure of a solution containing nonvolatile solute is proportional to mole fraction of solvent (b) Lowering of vapour pressure of solution containing nonvolatile solute is proportional to mole fraction of solute (c) Relative lowering of vapour pressure is equal to mole fraction of solute

When some amount of non-volatile solute is dissolved in a solvent to prepare a dilute solution, the vapour pressure of the solvent is lowered and it is directly proportional to the mole fraction of solvent in the solution . Relative lowering in vapour pressure is equal to mole fraction of solute . Elevation in boiling point of solvent is a collgative property like lowering in vaour pressure of solvent in solution , K_(b) i.e., molal elevation constant is calculated by the formula, K_(b)=DeltaT_(b)// molality and also by the expression, K_(b)=RT_(b)^(2)//1000l_(v) where T_(b) is boiling point of solvent and I_(v) is latent heat of vapourisation for 1 gm solvent . Abnormal elevation is boiling point =iX elevation in boiling point in ideal solution where i=van't Hoff factor Lowering in vapour pressure in an experiment was found to be x mm of Hg. It is : Lowering in vapour pressure in an experiment was found to be x mm of Hg. It is

When some amount of non-volatile solute is dissolved in a solvent to prepare a dilute solution, the vapour pressure of the solvent is lowered and it is directly proportional to the mole fraction of solvent in the solution . Relative lowering in vapour pressure is equal to mole fraction of solute . Elevation in boiling point of solvent is a collgative property like lowering in vaour pressure of solvent in solution , K_(b) i.e., molal elevation constant is calculated by the formula, K_(b)=DeltaT_(b)// molality and also by the expression, K_(b)=RT_(b)^(2)//1000l_(v) where T_(b) is boiling point of solvent and I_(v) is latent heat of vapourisation for 1 gm solvent . Abnormal elevation is boiling point =iX elevation in boiling point in ideal solution where i=van't Hoff factor Relative lowering in vapour pressure :

When some amount of non-volatile solute is dissolved in a solvent to prepare a dilute solution, the vapour pressure of the solvent is lowered and it is directly proportional to the mole fraction of solvent in the solution . Relative lowering in vapour pressure is equal to mole fraction of solute . Elevation in boiling point of solvent is a collgative property like lowering in vaour pressure of solvent in solution , K_(b) i.e., molal elevation constant is calculated by the formula, K_(b)=DeltaT_(b)// molality and also by the expression, K_(b)=RT_(b)^(2)//1000l_(v) where T_(b) is boiling point of solvent and I_(v) is latent heat of vapourisation for 1 gm solvent . Abnormal elevation is boiling point =iX elevation in boiling point in ideal solution where i=van't Hoff factor Molal elevation (K_(b))

AAKASH SERIES-SOLUTIONS -Objective Exercise -4
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