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Which of the following statements are fa...

Which of the following statements are false:

A

The radius of a metal atom is taken as half the nearest metal-metal distance in a metallic crystal.

B

One tetrahedral void per atom is present in hcp structure.

C

In the fluorite structure `(CaF_(2))`, the `Ca^(2+)` ions are located at the lattice points and the fluoride ions fill all the tetrahedral holes in the cep crystal.

D

In the antifluorite structure `(Li_(2)O, Rb_(2)S)` the cations are located at the lattice points and anions fill the tetrahedral holes in the ccp structure.

Text Solution

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The correct Answer is:
B, D

b) For HCP if these are .n.atoms per unit cell then the no of tetrahedral voids are 2n. So these is 2n tetrahedral voids per atom.
d) In antifluorite structure cation fill the tetrahedral  holes not anions.
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AAKASH SERIES-SOLID STATE-LEVEL - II LECTURE SHEET (EXERCISE - I)
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  2. A non-stoichiometric compound Cu(1.8)S is formed due to incorporation ...

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  3. Consider following statements I: If three Fe^(2+) are missing from i...

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  4. The n-type semiconductor is obtained when Si is doped with

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  5. Superconductors are technologically and commercially important substan...

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  6. When ferromagnetic substances are heated strongly, its magnetic moment

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  7. Silica (SiO(2)) can be crystalline as well as amorphous, with followin...

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  8. In a face centred cubic arrangement of A and B atoms whose A atoms are...

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  9. Which of the following statements are false:

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  10. Edge length of NaCl unit cell is 552 pm. Then which are correct statem...

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  11. Which is true

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  12. A metallic element crystallises into a lattice containing a sequence o...

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  13. In an FCC unit cell atoms are numbered as shown below the atoms not to...

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  14. Ice crystallises in a hexagonal lattice having volume of the unit cell...

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  15. For the structure of solid given below if the lattice points represent...

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  16. A certain solid mixed oxide crystallising in the cubic system contains...

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  17. It is stated that ZnS does not crystallise in the NaCl structure. It i...

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  18. Frenkel defect appears in

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  19. An electron trapped in an anion vacancy within the crystal is called.....

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  20. The presence of F-centres in a crystal makes it

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