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Edge length of NaCl unit cell is 552 pm....

Edge length of NaCl unit cell is 552 pm. Then which are correct statements

A

distance between `Na^(+)` and `Cl^(-)` ions is 276 pm

B

radii of `Na^(+) and Cl^(-)` ion will be 95 pm and 181 pm

C

nearest distance between two `Na^(+)` ions is `276sqrt2` pm

D

nearest distance between `Cl^(-)` ions is `95sqrt2` pm

Text Solution

Verified by Experts

The correct Answer is:
A, B, C

For `NaCl a=2r_(C )+2r_(q), a=2r_(c )+2r_(a)=552 p m,r_(c )+r_(a)=276 p m`
In NaCl radius ratio `(r_(c ))/(r_(a))=0.52,(r_(c ))/(r_(a))=(95)/(181)`
Nearest distance between two `Na^(+)` ions is the distance from body centre to edge centre is Hypotenuse in a right angled triangle i.e.`sqrt((276)^(2)+(276)^(2))=276sqrt2 p m`.
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