Home
Class 12
CHEMISTRY
It is stated that ZnS does not crystalli...

It is stated that ZnS does not crystallise in the NaCl structure. It is due to

A

The `(r_(+))/(r_(-))` ratio is 0.402, too low to avoid anion- anion contact in the NaCl structure

B

ZnS is water insoluble, NaCl is water soluble

C

ZnS is water soluble, NaCl is water insoluble

D

Zn belongs to d-block, Na belongs to s-block

Text Solution

Verified by Experts

The correct Answer is:
A

Because to have C.N. .6. and NaCl type structure radius ratio should be `0.414((r_(c ))/(r_(a)))`
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    AAKASH SERIES|Exercise LEVEL - II LECTURE SHEET (EXERCISE - II)|6 Videos
  • SOLID STATE

    AAKASH SERIES|Exercise LEVEL - II LECTURE SHEET (EXERCISE - III)|5 Videos
  • SOLID STATE

    AAKASH SERIES|Exercise LEVEL - I (EXERCISE - II)|77 Videos
  • REVISION EXERCISE

    AAKASH SERIES|Exercise COMPLEX COMPOUNDS|47 Videos
  • SOLIDS STATE

    AAKASH SERIES|Exercise PRACTICE EXERCISE|63 Videos

Similar Questions

Explore conceptually related problems

Ionic substance AB crystallises in rock salt structure. If all ions at the centre of the faces and at the body centre are removed, what should be the percentage of number of ions remained?

What is the crystal structure of NaCl ?

Boron does not occur in the free state. Why?

What is the crystal structure of NaCl?

Which of the following does not contain a symmetrical structure ?

Which of the following does not contain a symmetrical structure ?

What does a line spectrum tell us about the structure of an atom?

A compound of two elements P and Q crystallises in cubic structure. If P occupies corners and occupies face centres, what is the composition of the compound ? If atoms of Q along with one direction are removed, what is the composition ?

The positions of Cl^(-) ions in NaCl structure are

A compound having elements X and Y crystallises in a cubic structure, where X is at the corneer position and Y is at the center of the cube. The correct formula of the compound is

AAKASH SERIES-SOLID STATE-LEVEL - II LECTURE SHEET (EXERCISE - I)
  1. In face centered cubic structure, the octahedral voids are located at ...

    Text Solution

    |

  2. A non-stoichiometric compound Cu(1.8)S is formed due to incorporation ...

    Text Solution

    |

  3. Consider following statements I: If three Fe^(2+) are missing from i...

    Text Solution

    |

  4. The n-type semiconductor is obtained when Si is doped with

    Text Solution

    |

  5. Superconductors are technologically and commercially important substan...

    Text Solution

    |

  6. When ferromagnetic substances are heated strongly, its magnetic moment

    Text Solution

    |

  7. Silica (SiO(2)) can be crystalline as well as amorphous, with followin...

    Text Solution

    |

  8. In a face centred cubic arrangement of A and B atoms whose A atoms are...

    Text Solution

    |

  9. Which of the following statements are false:

    Text Solution

    |

  10. Edge length of NaCl unit cell is 552 pm. Then which are correct statem...

    Text Solution

    |

  11. Which is true

    Text Solution

    |

  12. A metallic element crystallises into a lattice containing a sequence o...

    Text Solution

    |

  13. In an FCC unit cell atoms are numbered as shown below the atoms not to...

    Text Solution

    |

  14. Ice crystallises in a hexagonal lattice having volume of the unit cell...

    Text Solution

    |

  15. For the structure of solid given below if the lattice points represent...

    Text Solution

    |

  16. A certain solid mixed oxide crystallising in the cubic system contains...

    Text Solution

    |

  17. It is stated that ZnS does not crystallise in the NaCl structure. It i...

    Text Solution

    |

  18. Frenkel defect appears in

    Text Solution

    |

  19. An electron trapped in an anion vacancy within the crystal is called.....

    Text Solution

    |

  20. The presence of F-centres in a crystal makes it

    Text Solution

    |