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Each rubidium halide crystallising in th...

Each rubidium halide crystallising in the RbCl type lattice has a unit cell length `0.30Å` greater than that for corresponding potassium salt `(r_(K^(+))=1.33Å)` of the same halogen. Hence, ionic radius of `Rb^(+)` is 

A

`1.18Å`

B

`1.48Å`

C

`1.63Å`

D

`1.03Å`

Text Solution

Verified by Experts

The correct Answer is:
B

RbCl type: `2Rb^(+) + 2Cl^(-)` = Edge length
KCl type : `2K^(+) + 2Cl^(-)` = Edge length
Edge length of `RbCl gt KCl` by `0.3 A`
`2Rb^(+) + 2Cl^(-)= x+0.3 , 2Rb^(+) -2 xx 1.33 = 0.3`
`2Rb^(+) = 2.96 A : Rb^(+) = 1.48 A`
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