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Which of the following statment(s) is (a...

Which of the following statment(s) is (are) correct?  

A

When the radius ratio is in the range `0.414 - 0.732`, a B.C.C arrangement with co-ordination no.8

B

When the radius ratio is in the range `0.225 -0.414,` a tetrahedral arrangement with co-ordination no. 4.

C

When the radius ratio is in the range 0.155 - 0.225, an octahedral arrangement with co-ordination no. 6.

D

In `B_(2)O_(3)`, smaller cations occupy triangular voids and a planar trigonal arrangement with co-ordination no.3

Text Solution

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The correct Answer is:
B, D

Radius ratio = 0.414-0.732 C.N = 6 octahedral
0.225-0.414 Tetrahedral C.N = 4
In `B_(2)O_(3)` smaller cations occupy triangular voids and a planar trigonal arrangement with C.N = 3
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  11. Following is the fact about the newly discovered superconductor of C(6...

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