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Select the correct expressions among the...

Select the correct expressions among the following

A

`(Delta G - Delta H)/(T) = ((del Delta G)/(del T))_(P)`

B

`(Delta G -Delta H)/(T ) = ((del Delta G)/(del T))_(V)`

C

`(Delta S)/(nF) = ((del E_("cell"))/(del T))_(P)`

D

`((del T)/(del P))_(H) = (-((del H)/(del P))_(T))/(C_(P))`

Text Solution

Verified by Experts

The correct Answer is:
A, C, D

`((del Delta G)/(del T))_(P) = - Delta S rArr Delta G = Delta H + T ((del Delta G)/(del T))_(P)`
`rArr ((del Delta G)/(del T))_(P) = (Delta G- Delta H)/(T)`
`Delta G = - n FE_("cell")`
`rArr ((del Delta G)/(del T))_(P) = nF ((del E_("cell"))/(del T))_(P) = - Delta S`
`rArr (Delta S)/(nF) = ((del E_("cell"))/(del T))_(P)`
`((del T)/(del P))_(H) = mu_(JT) = ((-del H)/(del P))_(T) xx (1)/(C_(P))`
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