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Out of C and CO which is a better reduci...

Out of C and CO which is a better reducing agent for ZnO ?

Text Solution

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From Ellingham diagram,
At temperature above 1120 K,
`Delta_f G_((C","CO))^(@) < Delta_fG_((Zn"," ZnO))^@` and at temperature above 1323 K
`Delta_fG_((C"," CO_2)) < Delta_fG_((Zn"," ZnO))^(@)`
However, `Delta_fG_((CO"," CO_2)) < Delta_fG_((Zn"," ZnO))^(@)`
Hence, carbon is better reducing agent than CO. The reduction of zinc is carried out at 1673 K.
`ZnO + C overset(1673 K)(rarr) Zn + CO`.
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KUMAR PRAKASHAN-GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS-SECTION - C (TEXTUAL EXERCISE)
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  2. Write chemical reactions taking place in the extraction of zinc from z...

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  3. State the role of silica in the metallurgy of copper.

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  4. What is meant by the term "Chromatography" ?

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  5. What criterion is followed for the selection of the stationary phase i...

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  6. Describe a method for refining nickel.

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  7. How can you separate alumina from silica in a bauxite ore associated w...

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  8. Giving examples, differentiate between ‘roasting' and 'calcination'.

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  9. How is 'cast iron' different from 'pig iron' ?

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  10. Differentiate between "minerals" and "ores".

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  11. Why copper matte is put in silica lined converter ?

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  12. What is the role of cryolite in the metallurgy of aluminium ?

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  13. How is leaching carried out in case of low grade copper ores ?

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  14. Why is zinc not extracted from zinc oxide through reduction using CO ?

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  15. The value of Delta G^@ for formation of Cr2O3 is -540 kJ mol^(-1) and ...

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  16. Out of C and CO which is a better reducing agent for ZnO ?

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  17. The choice of a reducing agent in a particular case depends on thermod...

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  18. Name the processes from which chlorine is obtained as a by-product. Wh...

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  19. What is the role of graphite rod in the electro metallurgy of aluminiu...

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  20. Predict conditions under which Al might be expected to reduce MgO.

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