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Passage-IV : Sulphur and rest of the e...

Passage-IV :
Sulphur and rest of the elements of group 16 are less electronegative than oxygen. Therefore, their atoms cannot take up electrons easily. They can acquire `ns^(2)np^(6)` configuration by sharing two electrons with the atoms of other elements and thus, exhibit +2 oxidation state in their compounds. In addition to this, their atoms have vacant d-orbitals in their valence shell to which electrons can be promoted from the p and s-orbitals of the shell. As a result, they can show +4 and +6 oxidation states shell.
Like sulphur, oxygen does not show +4 and +6 oxidation states. The reason is :

A

that oxygen is a gas while sulphur is a solid

B

that oxygen has high ionization enthalpies in comparison to sulphur

C

that oxygen has high electron affinity in comparison to sulphur

D

that oxygen has no d-orbitals in its valence shell

Text Solution

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The correct Answer is:
D

Due to the absence of vacant d-orbitals oxygen forms only stable compounds in valency of 2.
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Passage-IV : Sulphur and rest of the elements of group 16 are less electronegative than oxygen. Therefore, their atoms cannot take up electrons easily. They can acquire ns^(2)np^(6) configuration by sharing two electrons with the atoms of other elements and thus, exhibit +2 oxidation state in their compounds. In addition to this, their atoms have vacant d-orbitals in their valence shell to which electrons can be promoted from the p and s-orbitals of the shell. As a result, they can show +4 and +6 oxidation states shell. The nature of the compounds of sulphur having +4 oxidation state is :

No two electrons in an atom can have _______

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What are the elements of VIA group ? Write their valency shell electronic configurations

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The valence shell electronic configuration of VA group elements is :

AAKASH SERIES-VIA GROUP ELEMENTS-LEVEL-II LECTURE SHEET (EXERCISE-II Linked Comprehension type questions )
  1. Passage-III : The binary compounds of oxygen with other elements ar...

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  2. Passage-III : The binary compounds of oxygen with other elements ar...

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  3. Passage-III : The binary compounds of oxygen with other elements ar...

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  4. Passage-III : The binary compounds of oxygen with other elements ar...

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  5. Passage-IV : Sulphur and rest of the elements of group 16 are less e...

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  6. Passage-IV : Sulphur and rest of the elements of group 16 are less e...

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  7. Passage - V: Reference to the above flow diagram whit ppt (D) is ...

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  8. Passage - V: Reference to the above flow diagram Gas (C ) is

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  9. Passage - V: Reaction, C to G is

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  10. Passage - VI : Industrially sulphuric acid is produced by the follow...

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  11. Passage - VI : Industrially sulphuric acid is produced by the follow...

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  12. Passage - VI : Industrially sulphuric acid is produced by the follow...

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  13. Passage - VII : An aqueous solution of a gas (x) gives the followin...

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  14. Passage - VII : An aqueous solution of a gas (x) gives the followin...

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  15. Passage - VII : An aqueous solution of a gas (x) gives the followin...

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  16. Passage - VII : An aqueous solution of a gas (x) gives the followin...

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  17. Passage - VIII : In this passage five observation are given. Questio...

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  18. Passage - VIII : In this passage five observation are given. Questio...

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  19. Passage - VIII : In this passage five observation are given. Questio...

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  20. Passage - VIII : In this passage five observation are given. Questio...

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