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{:("COLUMN-I","COLUMN-II"),((A)SO(2),(p)...

`{:("COLUMN-I","COLUMN-II"),((A)SO_(2),(p)"+2 and '0' states of 'S' "),((B)H_(2)S,(q)"Trimer solid"),((C )SO_(3), (r )"Reductant"),((D)S_(6)O,(s)"Oxidant"),(,(t)sp^(2)"sulphur"):}`

Text Solution

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The correct Answer is:
A-r,s,t; B-r; C-q,s,t; D-p,r,st
A-r,s,t- `SO_(2)` - Act as reductant. Oxidant and the sulphur. Undergo `sp^(2)` hybridisation
B-r - `H_(2)S` - It act as only oxidant
C-q,s,t - `SO_(3)` - In the solid state it exist as Trimer `(S_(3)O_(9))`. It act as oxidant and undergo `sp^(2)` - hybridization.
D-p,r,s,t
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{:("COLUMN-I","COLUMN-II"),((A)SO_(2),(p)"Acidic nature"),((B)SO_(3),(q)"Oxidising agent"),((C )O_(3),(r )"Reducing agent"),((D)O_(2)^(-2),(s) "Bleaching agent"):}

Na_(2)S_(2)O_(3) may react with the compound given in Column-I, Na_(2)S_(2)O_(3) exhibits the properties of the type give in the coloumn-II, matter the reactants given in column-I with the type of property, properties given in Column-II {:("COLUMN-I","COLUMN-II"),((A)SO_(2),(p)"turns acidified "K_(2)Cr_(2)O_(7)" solution green"),((B)CO_(2),(q)"turns blue is Red"),((C )H_(2)S,(r )"turns lime water milky"),((D)H_(2)O_(2),(s) "used for restoring old paintings in the museums"):}

{:("COLUMN-I","COLUMN-II"),((A)H_(2)S_(2)O_(5),(p)"Dibasic"),((B)H_(2)S_(2)O_(4),(q)S-O-S " bond"),((C )H_(2)S_(4)O_(6),(r )S-S" bond with same oxidation state of sulphur"),((D)H_(2)S_(2)O_(7),(s) S-S " bond with different oxidation state of sulphur"),(,(t)"Atleast one 'S' in +6 oxidation state"):}

{:("COLUMN-I","COLUMN-II"),("(Oxy-acid of S)","(Oxidation state of 'S'')"),((A)H_(2)SO_(3),(p)+2),((B)H_(2)S_(2)O_(6),(q)+3),((C )H_(2)S_(2)O_(3),(r )+4),((D)H_(2)S_(2)O_(4),(s) +5):}

{:("COLUMN-I","COLUMN-II"),("(Compound)","(Use)"),((A)SO_(2),(p)"Antichlor"),((B)"Hypo",(q)"reducing agent"),((C )"Ozone",(r )"Purification of water"),((D)H_(2)SO_(4),(s) "Dehydrating agent"):}

{:("COLUMN-I","COLUMN-II"),((A)S_(2)Cl_(2),(p)"gives mustard gas with "C_(2)H_(4)),((B)SF_(6),(q)"gives dibasic acid on hydrolysis"),((C )SCl_(4),(r )"uniform bond angles"),((D)SCl_(2),(s) "Disproportionates on hydrolysis"):}

{:("COLUMN-I","COLUMN-II"),("A)"Cl_(2)O,"p) Linear shape"),("B)" BrO_(2)^(+),"q)" sp^(3)-"hybridisation"),("C)" ClF_(3),"r)" sp^(2)-"hybridisation"),("D)" I_(3)^(-),"s)" sp^(3)d-"hybridisation"):}

Oxidation states of S in H_(2)S_(2)O_(7) are

{:("COLUMN-I","COLUMN-II"),("A)" PCl_(5),"p)" sp^(3)),("B)" ClO_(4)^(-),"q) Tetrahedral"),("C)" XeF_(2),"r) Trigonol bipyramidal"),("D)" SO_(4)^(-2),"s)" sp^(3)d):}

Match the following {:("COLUMN-I","COLUMN-II"),("A)" F_(2)O,"p)" SP^(2)-"Hybridisation"),("B)" ClO_(2),"q)" SP^(3)-"Hybridisation"),("C)"BrF_(3),"r)" SP^(3)d^(2)-"Hybridisation"),("D)"IF_(5),"s)" SP^(3)d-"Hybridisation"):}