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Passage - VI : Industrially sulphuric ...

Passage - VI :
Industrially sulphuric acid is produced by the following steps:
Stage I : `S+O_(2) overset(Delta)to SO_(2)`
Stage II : `2SO_(2) +O_(2) overset(V_(2)O_(5))to 2SO_(3)`
Stage III : `SO_(3)+H_(2)O to H_(2)SO_(4)`
Since the reaction between `SO_(3) and H_(2)O` is violent,
`SO_(3)` is passed into `98% H_(2)SO_(4)` to produce oleum `(H_(2)S_(2)O_(7))`
`H_(2)SO_(4)+PCl_(5) to (X) overset(H_(2)O)to ` two strong acids where 'x' is

A

`SO_(2)Cl_(2)`

B

SOCl

C

`ClSO_(3)H`

D

`POCl_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A

`SO_(2)Cl_(2)+2H_(2)O to 2HCl +H_(2)SO_(4)`
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Passage - VI : Industrially sulphuric acid is produced by the following steps: Stage I : S+O_(2) overset(Delta)to SO_(2) Stage II : 2SO_(2) +O_(2) overset(V_(2)O_(5))to 2SO_(3) Stage III : SO_(3)+H_(2)O to H_(2)SO_(4) Since the reaction between SO_(3) and H_(2)O is violent, SO_(3) is passed into 98% H_(2)SO_(4) to produce oleum (H_(2)S_(2)O_(7)) Pure H_(2)SO_(4) does not react with metal because -

Passage - VI : Industrially sulphuric acid is produced by the following steps: Stage I : S+O_(2) overset(Delta)to SO_(2) Stage II : 2SO_(2) +O_(2) overset(V_(2)O_(5))to 2SO_(3) Stage III : SO_(3)+H_(2)O to H_(2)SO_(4) Since the reaction between SO_(3) and H_(2)O is violent, SO_(3) is passed into 98% H_(2)SO_(4) to produce oleum (H_(2)S_(2)O_(7)) Ionically the reaction between H_(2)SO_(4) & Mg may be presented as, Mg+2H_(3)O^(+) to Mg^(2+)+H_(2) uarr +2H_(2)O Therefore, in the given reaction -

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