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Passage - II : Sulphur forms hexahalid...

Passage - II :
Sulphur forms hexahalides, tetrahalides, dihalides and monohalides, sulphur forms only hexa fluorides but not hexachlorides, hexa bromides and hexaiodides. Sulphur halides tend to hydrolyse easily. Sulphur hexa fluorides is an exception.
Of the oxohalides, the most important are those of sulphur especially sulphur dichloride oxide (Thionyl chloride) `SOCl_(2)` and sulphurdichloride dioxide (Sulphuryl chloride) `SO_(2)Cl_(2)` these are also hydrolyse in water
`SO_(2)Cl_(2)` is dissolved in `H_(2)O` which of the following statement is wrong about the solution

A

Gives white ppt with `BaCl_(2)` in soluble in any acid

B

The solution contain two different type of acids a monobasic and dibasic acid

C

The solution can decolourize can decolourize the permanganate

D

The oxidaction states of the elements in `SO_(2)Cl_(2)` do not change when dissolve in water

Text Solution

Verified by Experts

The correct Answer is:
C

`SOCl_(2)+H_(2)O to 2HCl +H_(2)SO_(4)`. It does not decolorize `KMnO_(4)`.
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