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Dehydration of hydrates of halides of ca...

Dehydration of hydrates of halides of calcium, barium and strontium i.e., `CaCI_(2). 6H_(2)O, BaCI_(2).2H_(2)O, SrCI_(2).2H_(2)O`, can be achieved by heating. These become wet on keeping in air. Which of the following statements is correct about these halides?

A

Act as dehydrating agent

B

Can absorb moisture from air

C

Tendency to form hydrate decreases from calcium to barium

D

All of the above

Text Solution

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The correct Answer is:
To solve the question regarding the dehydration of hydrates of halides of calcium, barium, and strontium, let's break it down step by step: ### Step 1: Understanding the Compounds The compounds in question are: - Calcium chloride hexahydrate: \( \text{CaCl}_2 \cdot 6\text{H}_2\text{O} \) - Barium chloride dihydrate: \( \text{BaCl}_2 \cdot 2\text{H}_2\text{O} \) - Strontium chloride dihydrate: \( \text{SrCl}_2 \cdot 2\text{H}_2\text{O} \) These compounds contain water of crystallization, which can be removed by heating. ### Step 2: Dehydration Process When these hydrates are heated, they lose their water molecules: - \( \text{CaCl}_2 \cdot 6\text{H}_2\text{O} \) becomes \( \text{CaCl}_2 \) (anhydrous) - \( \text{BaCl}_2 \cdot 2\text{H}_2\text{O} \) becomes \( \text{BaCl}_2 \) (anhydrous) - \( \text{SrCl}_2 \cdot 2\text{H}_2\text{O} \) becomes \( \text{SrCl}_2 \) (anhydrous) ### Step 3: Hygroscopic Nature The question states that these compounds become wet when kept in air. This is due to their hygroscopic nature, which means they can absorb moisture from the atmosphere. ### Step 4: Correct Statements Now, we need to evaluate the statements about these halides: 1. They are dehydrating agents and can absorb moisture from the air. 2. The tendency to form hydrates decreases from calcium to barium. Both statements are correct: - The first statement is true because these compounds can absorb water from the air. - The second statement is also true because the ability to form hydrates decreases as we move down the group from calcium to barium due to decreasing hydration energy. ### Conclusion Thus, both statements about the halides are correct. ---

To solve the question regarding the dehydration of hydrates of halides of calcium, barium, and strontium, let's break it down step by step: ### Step 1: Understanding the Compounds The compounds in question are: - Calcium chloride hexahydrate: \( \text{CaCl}_2 \cdot 6\text{H}_2\text{O} \) - Barium chloride dihydrate: \( \text{BaCl}_2 \cdot 2\text{H}_2\text{O} \) - Strontium chloride dihydrate: \( \text{SrCl}_2 \cdot 2\text{H}_2\text{O} \) ...
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