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Which of the following compounds are rea...

Which of the following compounds are readily soluble in water?

A

`BeSO_(4)`

B

`MgSO_(4)`

C

`BaSO_(4)`

D

`SrSO_(4)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds are readily soluble in water, we need to analyze the solubility of compounds formed by Group 2 elements (alkaline earth metals) based on their lattice energy and hydration energy. ### Step-by-Step Solution: 1. **Identify the Compounds:** Let's assume the compounds given in the options are: - A) Beryllium sulfate (BeSO₄) - B) Magnesium sulfate (MgSO₄) - C) Strontium sulfate (SrSO₄) - D) Barium sulfate (BaSO₄) 2. **Understand Lattice Energy and Hydration Energy:** - **Lattice Energy:** This is the energy required to separate one mole of a solid ionic compound into its gaseous ions. Higher lattice energy means the compound is less soluble. - **Hydration Energy:** This is the energy released when gaseous ions are surrounded by water molecules. Higher hydration energy means the compound is more soluble. 3. **Analyze Hydration Energy Trends:** - As we move down the group from beryllium to barium, the size of the cations increases. - Consequently, the hydration energy decreases because larger cations are less effectively solvated by water molecules. 4. **Compare Hydration Energies:** - **Beryllium (Be²⁺)** and **Magnesium (Mg²⁺)** have relatively high hydration energies due to their smaller ionic sizes. - **Strontium (Sr²⁺)** and **Barium (Ba²⁺)** have lower hydration energies because they are larger cations. 5. **Determine Solubility:** - Since beryllium and magnesium have high hydration energies, they can easily compensate for their lattice energies, making **Beryllium sulfate (BeSO₄)** and **Magnesium sulfate (MgSO₄)** soluble in water. - On the other hand, strontium and barium have low hydration energies, which do not compensate for their lattice energies, making **Strontium sulfate (SrSO₄)** and **Barium sulfate (BaSO₄)** less soluble or insoluble in water. 6. **Conclusion:** Based on the analysis, the compounds that are readily soluble in water are: - **Beryllium sulfate (BeSO₄)** - **Magnesium sulfate (MgSO₄)** ### Final Answer: The compounds that are readily soluble in water are **Beryllium sulfate (BeSO₄)** and **Magnesium sulfate (MgSO₄)**.

To determine which of the given compounds are readily soluble in water, we need to analyze the solubility of compounds formed by Group 2 elements (alkaline earth metals) based on their lattice energy and hydration energy. ### Step-by-Step Solution: 1. **Identify the Compounds:** Let's assume the compounds given in the options are: - A) Beryllium sulfate (BeSO₄) - B) Magnesium sulfate (MgSO₄) ...
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