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Benzophenone can be obtained by ……...

Benzophenone can be obtained by ……

A

`"benzoyl chloride"+ "benzene"+ AlCl_(3)`

B

`"benzoyl chloride"+"diphenyl cadmium"`

C

`"benzoyl chloride" + "phenyl magnesium chloride"`

D

`"benzene" + "carbon monoxide" + ZnCl_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine how benzophenone can be obtained, we will analyze the provided options step by step. ### Step 1: Understand the Structure of Benzophenone Benzophenone has the structure of two benzene rings (C6H5) connected by a carbonyl group (C=O). Its chemical formula is C13H10O. ### Step 2: Analyze Option A **Option A:** Benzoyl chloride + Benzene + AlCl3 - **Benzoyl chloride (C6H5C(=O)Cl)** is a reactive acyl chloride. - **Aluminum chloride (AlCl3)** acts as a Lewis acid and facilitates the Friedel-Crafts acylation reaction. - In this reaction, benzoyl chloride reacts with benzene in the presence of AlCl3, leading to the formation of benzophenone through the following steps: 1. AlCl3 coordinates with the chlorine atom of benzoyl chloride, forming a complex. 2. The complex generates a highly reactive acylium ion (C6H5C+=O). 3. The acylium ion attacks the benzene ring, leading to the formation of benzophenone and HCl as a byproduct. **Conclusion for Option A:** This method successfully produces benzophenone. ### Step 3: Analyze Option B **Option B:** Benzoyl chloride + Diphenyl calcium - **Diphenyl calcium** is a compound that can provide phenyl groups. - The reaction proceeds similarly to Option A, where the phenyl group from diphenyl calcium attacks the carbonyl carbon of benzoyl chloride, leading to the formation of benzophenone. - The chloride ion is eliminated in the process. **Conclusion for Option B:** This method also successfully produces benzophenone. ### Step 4: Analyze Option C **Option C:** Benzoyl chloride + Phenyl magnesium chloride - **Phenyl magnesium chloride (C6H5MgCl)** is a Grignard reagent. - In this case, the nucleophilic phenyl group is not stable enough to effectively attack the carbonyl carbon of benzoyl chloride. - As a result, this reaction does not yield benzophenone. **Conclusion for Option C:** This method does not produce benzophenone. ### Step 5: Analyze Option D **Option D:** Benzene + Carbon monoxide + ZnCl2 - This reaction resembles the Kolbe electrolysis and is not suitable for forming benzophenone. - Instead, it leads to the formation of benzoic acid. **Conclusion for Option D:** This method does not produce benzophenone. ### Final Conclusion The methods that can produce benzophenone are: - **Option A:** Benzoyl chloride + Benzene + AlCl3 - **Option B:** Benzoyl chloride + Diphenyl calcium ### Summary of Correct Options The correct options for obtaining benzophenone are A and B. ---

To determine how benzophenone can be obtained, we will analyze the provided options step by step. ### Step 1: Understand the Structure of Benzophenone Benzophenone has the structure of two benzene rings (C6H5) connected by a carbonyl group (C=O). Its chemical formula is C13H10O. ### Step 2: Analyze Option A **Option A:** Benzoyl chloride + Benzene + AlCl3 ...
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Knowledge Check

  • Benzene can be obtained by :

    A
    `C_(6)H_(5)OH + NaOH underset(Delta)overset(CuO)to`
    B
    `C_(6)H_(5)OH + Zn overset(Delta)`
    C
    `C_(6)H_(5) - N = N - Cl + H_(2)O to`
    D
    All of these
  • Acetophenone can be obtained by the distillation of

    A
    `(C_(6)H_(5)COO)_(2)Ca`
    B
    `(CH_(3)COO)_(2)Ca`
    C
    `(C_(6)H_(5)COO)_(2)` and` (CH_(3)COO)_(2)Ca`
    D
    `(C_(6)H_(5)CO)_(2)Ca` and `(HCOO)_(2)Ca`
  • Iodobenzene can be obtained by :

    A
    B
    C
    D
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