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Assertion (A) Formaldehyde is a planar m...

Assertion (A) Formaldehyde is a planar molecule.
Reason (R) It contains `sp^(2)` hybridised carbon atom.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect, but (R) is correct.

Text Solution

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The correct Answer is:
To solve the question regarding the assertion and reason related to formaldehyde, we will break it down step by step. ### Step 1: Understand the Structure of Formaldehyde Formaldehyde has the molecular formula \( H_2CO \). Its structure can be represented as: ``` H | H--C==O ``` In this structure, the carbon atom is double-bonded to an oxygen atom and single-bonded to two hydrogen atoms. **Hint:** Identify the molecular formula and draw the structure to visualize the bonding. ### Step 2: Determine the Hybridization of the Carbon Atom The carbon atom in formaldehyde forms: - 1 double bond with oxygen (which consists of 1 sigma bond and 1 pi bond) - 2 single bonds with hydrogen atoms (2 sigma bonds) Thus, the carbon atom forms a total of 3 sigma bonds. **Hint:** Count the number of sigma bonds to determine the steric number. ### Step 3: Calculate the Steric Number The steric number is calculated as follows: \[ \text{Steric Number} = \text{Number of Sigma Bonds} + \text{Number of Lone Pairs} \] In formaldehyde, there are 3 sigma bonds and no lone pairs on the carbon atom: \[ \text{Steric Number} = 3 + 0 = 3 \] **Hint:** Remember that lone pairs on the central atom also contribute to the steric number. ### Step 4: Determine the Hybridization Based on Steric Number A steric number of 3 indicates that the hybridization of the carbon atom is \( sp^2 \). This hybridization leads to a trigonal planar geometry. **Hint:** Use the steric number to identify the type of hybridization and the corresponding molecular geometry. ### Step 5: Conclude the Planarity of the Molecule Since the carbon atom in formaldehyde is \( sp^2 \) hybridized, it adopts a trigonal planar shape, which means that all atoms bonded to the carbon atom lie in the same plane. Therefore, formaldehyde is indeed a planar molecule. **Hint:** Connect the hybridization type to the molecular geometry to confirm the planarity. ### Final Conclusion - **Assertion (A)**: Formaldehyde is a planar molecule. **(True)** - **Reason (R)**: It contains \( sp^2 \) hybridized carbon atom. **(True)** - The reason correctly explains the assertion. Thus, the correct answer is that both A and R are correct, and R is the correct explanation of A.

To solve the question regarding the assertion and reason related to formaldehyde, we will break it down step by step. ### Step 1: Understand the Structure of Formaldehyde Formaldehyde has the molecular formula \( H_2CO \). Its structure can be represented as: ``` H | H--C==O ...
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