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Assertion (A) Aldehydes and ketones, bot...

Assertion (A) Aldehydes and ketones, both react with Tollen's reagent to form silver mirror.
Reason (R) Both, aldehydes and ketones contain a carbonyl group.

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To solve the assertion and reason question, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that "Aldehydes and ketones both react with Tollen's reagent to form a silver mirror." - **Understanding Tollen's Reagent**: Tollen's reagent (Ag(NH3)2^+) is a mild oxidizing agent that is primarily used to test for aldehydes. When aldehydes are present, they reduce the silver ion to metallic silver, which forms a silver mirror on the surface of the test tube. - **Reaction with Ketones**: Ketones do not generally react with Tollen's reagent because they are not easily oxidized. Therefore, they do not produce a silver mirror. **Conclusion for Assertion**: The assertion is **incorrect** because only aldehydes react with Tollen's reagent to form a silver mirror, while ketones do not. ### Step 2: Analyze the Reason The reason states that "Both aldehydes and ketones contain a carbonyl group." - **Understanding Carbonyl Group**: Both aldehydes (RCHO) and ketones (RC(=O)R') contain a carbonyl group (C=O). This is a common feature of both classes of compounds. - **Relevance to the Assertion**: While it is true that both contain a carbonyl group, this does not justify the assertion that both react with Tollen's reagent. **Conclusion for Reason**: The reason is **correct** because both aldehydes and ketones do contain a carbonyl group. ### Final Conclusion - The assertion is **incorrect**. - The reason is **correct**. ### Answer The correct option is **4**: Assertion is wrong, but the reason is correct. ---

To solve the assertion and reason question, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that "Aldehydes and ketones both react with Tollen's reagent to form a silver mirror." - **Understanding Tollen's Reagent**: Tollen's reagent (Ag(NH3)2^+) is a mild oxidizing agent that is primarily used to test for aldehydes. When aldehydes are present, they reduce the silver ion to metallic silver, which forms a silver mirror on the surface of the test tube. - **Reaction with Ketones**: Ketones do not generally react with Tollen's reagent because they are not easily oxidized. Therefore, they do not produce a silver mirror. ...
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NCERT EXEMPLAR ENGLISH-ALDEHYDE, KETONES AND CARBOXYLIC ACIDS-Short Answer Type Questions
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  4. Arrange the following in decreasing order of their acidic strength. Gi...

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  5. Alkenes and carbonyl compounds both contain a pi bond but alkenes sh...

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  6. Carboxylic acids contain carbonyl group but do not show the nucleophil...

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  7. Identify the compounds A, B and C in the following reaction : CH(3)-...

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  8. Why are carboxylic acids more acidic than alcohols or phenols although...

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  9. Complete the following reaction sequence : CH(3)-overset(O)overset(|...

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  10. Ethylbenzene is generally prepared by acetylation of benzene followed ...

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  11. Can Gattermann-Koch reaction be considered similar to Friedel Craft's ...

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  12. Match the common names given in Column I with the IUPAC names given in...

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  13. Match the acids given in Column I with their correct IUPAC names given...

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  14. Match the reactions given in Column I with the suitable reagents given...

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  15. Match the example given in Column I with the name of the reaction in C...

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  16. Assertion (A) Formaldehyde is a planar molecule. Reason (R) It conta...

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  17. Assertion (A) compound containing -CHO group are easily oxidised to co...

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  18. Assertion (A) The alpha-hydrogen atom in carbonyl compounds is less ac...

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  19. Assertion : Aromatic aldehydes and formaldehyde undergo Cannizzaro rea...

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  20. Assertion (A) Aldehydes and ketones, both react with Tollen's reagent ...

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