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Assertion (A) Hydrolysis of (-)-2-bromoo...

Assertion (A) Hydrolysis of (-)-2-bromooctane proceeds with inversion of configuration
Reason (R) This reaction proceeds through the formation of a carbocation.

A

Assertion and reason both are correct and reason is correct explanation of assertion

B

Assertion and reason both are wrong statements

C

Assertion is correct but reason is wrong statement

D

Assertion is wrong but reason is correct statement.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that the hydrolysis of (-)-2-bromooctane proceeds with inversion of configuration. - **Explanation**: In an SN2 reaction, the nucleophile (OH⁻ in this case) attacks the carbon atom that is bonded to the leaving group (Br) from the opposite side. This back-side attack leads to the inversion of configuration at the carbon center. Since (-)-2-bromooctane is a chiral molecule, the inversion of configuration means that the product will have the opposite configuration compared to the starting material. ### Step 2: Analyze the Reason The reason states that this reaction proceeds through the formation of a carbocation. - **Explanation**: In SN2 reactions, there is no formation of a carbocation. Instead, the nucleophile attacks the substrate directly, leading to a concerted mechanism where the bond to the leaving group breaks as the bond to the nucleophile forms. Carbocation formation is characteristic of SN1 reactions, not SN2. ### Step 3: Conclusion - The assertion is **true**: Hydrolysis of (-)-2-bromooctane does proceed with inversion of configuration. - The reason is **false**: This reaction does not proceed through the formation of a carbocation; it is an SN2 mechanism. ### Final Answer The assertion is correct, but the reason is incorrect. ---

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that the hydrolysis of (-)-2-bromooctane proceeds with inversion of configuration. - **Explanation**: In an SN2 reaction, the nucleophile (OH⁻ in this case) attacks the carbon atom that is bonded to the leaving group (Br) from the opposite side. This back-side attack leads to the inversion of configuration at the carbon center. Since (-)-2-bromooctane is a chiral molecule, the inversion of configuration means that the product will have the opposite configuration compared to the starting material. ### Step 2: Analyze the Reason ...
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